The use of nanomaterials, such as nanoparticles and nanotubes, for electrochemical detection of metal species has been investigated as a way of modifying electrodes by electrochemical stripping analysis. The present study develops a new methodology based on a comparative study of nanoparticles and nanotubes with differential pulse anodic stripping voltammetry (DPASV) and examines the simultaneo...

The title compound, {(C(14)H(18)N(2))[Pb(2)I(6)]}(n), consists of discrete 1,1'-dimethyl-4,4'-(ethane-1,2-di-yl)dipyridinium cations and one-dimensional [Pb(2)I(6)](n) anions. The organic cation has an inversion center at the mid-point of the ethane C-C bond. In the anion, the Pb(II) atom is coordinated by six I atoms in a distorted octa-hedral geometry. The I atoms bridge the Pb(II) atoms into...

1 Erratum Unfortunately [1], the title for Table 3 in the original version of this paper was incorrect. The correct title for Table three is 'The degree of adsorption of Zn(II), Cu(II), Fe(III), Cd(II), and Pb(II) cations by synthesized composites as a function of the medium acidity'. permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to...

When BaTiO3 is illuminated by ultraviolet light in aqueous solutions containing dissolved Pb2+ or Ag+ cations, photochemical reaction products are deposited on the surface in patterns that correspond to the underlying ferroelectric domain structure. On the basis of an analysis of the domain polarization, oxidized Pb and reduced Ag accumulate on the surfaces of domains with opposite polarization...

Dual-Functional Ag@Pt Nanozymes Two types of dual-functional nanozymes, adjustable NA-Ag@Pt nanozyme and POD-like enhancing FNA-Ag@Pt nanozyme, are designed synthesized by nucleic acid metal ions coordination-driven one-step rapid self-assembly. One the Pb-FNA-Ag@Pt nanozymes can achieve specific detection Pb2+ solve specificity problem both also potential antibacterial agents for biological fu...

In this study, a full-potential density functional theory was used to investigate the effects of Ti substitution by different cations. In both rutile and anatase, Ti atom was replaced by Ce, Au, Sn, Ag, Mo, Nb, Zr, and Y. Phase stability, electronic structure and formation energy of oxygen vacancy were compared for rutile and anatase. The results indicated that substitution of Ce and Zr increas...

Voltammetric ion-selective electrodes (ISEs) based on poly(3-octylthiophene) (POT) in connection with ultra-thin membranes formulated different selective receptors (i.e., ionophores) are proposed for detection of lead, copper and silver ions (Pb2+, Cu2+ Ag+). The working mechanism the POT-membrane electrode is interconnected charge transfer processes both sides membrane, overall process dependi...

The cyclic tetrasaccharide, cyclo-(-->6)-alpha-D-Glcp-(1-->3)-alpha-D-Glcp-(1-->6)-alpha-D-Glcp-(1-->3)-alpha-D-Glcp-(1-->), was oxidized in high yield to a dicarboxylic acid, cyclo-(-->6)-alpha-D-Glcp-(1-->3)-alpha-D-GlcpA-(1-->6)-alpha-D-Glcp-(1-->3)-alpha-D-GlcpA-(1-->). The parent and oxidized compound were then screened for the ability to form stable complexes with 20 metal cations. Ion-ex...

In this work, hydrogel nanocomposites were synthesized by solution polymerization of acrylic acid (AA) and itaconic acid (IA) in the presence of cotton fabric. Ammonium persulfate (APS) was used as the polymerization initiator in the presence of a crosslinker, methylene bisacrylamide (MBA). Insertion of Ag followed by reduction of Ag+ cations results in a hydrogel nanocomposite. The ...