Adsorption of CO on metal atoms surfaces is one of the most thoroughly studied adsorption systems. It is a prototypical model system for investigating molecular adsorption, and of fundamental importance in many catalytic reactions. However, real catalysts often consists of several components, and offer geometric and electronic properties different from the elemental surfaces. The Ni3Al(111) sur...

Differential scanning calorimetry (DSC), temperature programmed desorption mass spectrometry (TPD-MS) and small angle neutron scattering (SANS) were used to investigate CO2 uptake by the Wyodak coal. Adsorption of carbon dioxide on Wyodak coal was studied by DSC. The exotherms evident at low temperatures are associated with the uptake of CO2 suggesting that carbon diox...

A lignocellulose/montmorillonite (LMT) nanocomposite was prepared as a reusable adsorbent for cobalt(II) ions, and characterized by nitrogen (N₂) adsorption/desorption isotherm, X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FTIR). LMT exhibited efficient adsorption of cobalt ions (Co(II)), and th...

The nanocomposites of poly (Acryl amide-co-Acrylic acid) with different contents of NaAzeolite were prepared using ammonium persulfate as an initiator and N, N′-methylenebisacrylamide as the crosslinker. The morphology was characterized by SEM and the structure ofnanocomposite materials was studied with XRD and FT-IR that showed the interaction betweenporous materials and poly (AAm-co-Aac). The...

Copper trimesate (Cu-BTC) MOF has been pointed out as a promising adsorbent for separating carbon dioxide from methane. However, MOF’s need to be shaped prior to their use in packed bed adsorbers in order to reduce pressure drop; on the other hand, the production of mechanically resistant shaped bodies reduces their adsorption performance. In this work, Cu-BTC tablets provided by BASF are evalu...

The effect of aspartic acid on the adsorption of Pb(II), Cu(II), Zn(II), Co(II), and Mn(II) on kaolinite at 25 degrees C in the presence of 5 mM KNO3 was investigated by means of potentiometric titrations and adsorption measurements over a range of pH and concentration. Data were modeled by extended constant capacitance models. Aspartic acid slightly enhanced the adsorption of Pb(II), Zn(II), a...

A differentially pumped, capillary array molecular beam source is used to study the reversible adsorption of CO on CO/Pd~111! @Q(CO)50.55# and vinylidene/Pd~111! @Q(vinylidene)51.0# at 300 K. Differentially pumping allows the beam to equilibrate rapidly ~in ;2 s! while maintaining good beam uniformity. The isosteric heat of adsorption of reversibly held CO on a surface precovered with 0.55 mono...

In this paper, multiscale composites formed by grafting N-doped carbon nanotubes (CNs) on the surface of polyamide (PAN)-based activated carbon fibers (ACFs) were investigated and their adsorption performance for CO₂ was determined. The spaghetti-like and randomly oriented CNs were homogeneously grown onto ACFs. The pre-immersion of cobalt(II) ions for ACFs made the CNs grow above with a large ...

Understanding the adsorption phenomena of small adsorbates involved in surface reactions on transition metals is important because their adsorption strength can be a descriptor for predicting the catalytic activity. To explore adsorption energies on a wide range of binary transition metal alloys, however, tremendous computational efforts are required. Using density functional theory (DFT) calcu...

In this study, two Carbon Molecular Sieves using Pistachio shell (CMS P) and Walnut shell (CMS W) were prepared by a chemical vapor deposition method and used for pressure swing adsorption and separation of CO/H2 and CO/CH4. Adsorption isotherms of gases obtained for both CMS’s. The Dubinin-Radushkevich isotherm model was used for comparing pore volum...