A carboxylic acid based reversible additionfragmentation transfer (RAFT) agent is used to prepare gels composed of worm-like diblock copolymers using two non-ionic monomers, glycerol monomethacrylate (GMA) and 2-hydroxypropyl methacrylate (HPMA). Ionization of the carboxylic acid end-group on the PGMA stabilizer block induces a worm-to-sphere transition, which in turn causes immediate degelatio...

Solubilization and encapsulation of fullerenes C60 and C70 by ultralarge hollow micelles formed by rod-coil diblock copolymers and characterization of the resulting self-organized fullerene-block copolymer assemblies are reported. The solubilization capacity of each fullerene in poly(phenylquinoline)-blockpolystyrene (PPQ-PS) micelles in binary solvents, trifluoroacetic acid/dichloromethane, an...

Abstract Introduction: The use of membranes and transplant materials as scaffolds in periodontal regenerative surgeries is gaining an increasing application for restoring the structure and function of lost tissues. The present study aimed to evaluate the mechanical properties of PEG/MA (Polyethylene glycol/Maleic Acid) copolymer as a bioscaffold. Metho...

In an attempt to interact natural bone and bone cells with biomaterials and to begin to develop modular tissue engineering scaffolds, substrates containing phosphonate groups were identified to mimic mineral-protein and natural polymer-protein interactions. In this study, we investigated poly(vinyl phosphonic acid) copolymer integration with existing materials as a graft-copolymer surface modif...

The use of short chain block copolymer melts as nanostructured templates with sub-10 nm domains is often limited by their low segregation strength ( N). Since increasing molar mass to strengthen segregation also increases the interdomain spacing of block copolymer melts, it is more desirable to increase the Flory-Huggins segment-segment interaction parameter, , to produce strong segregation. We...

Superporous hydrogels (SPHs), based on poly(2-hydroxyethyl methacrylate) (PHEMA), were prepared by adding minute amounts of an ioncomplexable hydrophilic acrylic acid. PHEMA SPHs are generally strong, but their swelling is minimal. To improve the swelling, different poly(HEMA-coacrylic acid) hydrogels were polymerized and crosslinked, then physically treated with divalent calcium and trivalent ...

Chemical cross-linking of gelatin is achieved using a thermosensitive reactive copolymer based on N-isopropylacrylamide (NIPAM). The copolymer bears 5 mol % acrylic acid units which form amide bonds with the amino groups of gelatin in the presence of a water-soluble carbodiimide. The cross-linking reaction occurs only below the LCST congruent with 34 degrees C (lower critical solution temperatu...

A molecularly imprinted copolymer, poly(o-phenylenediamine-co-o-aminophenol) (PoPDoAP), was prepared as a new ascorbic acid (AA) sensor. The copolymer was synthesized by incorporation of AA as template molecules during the electrochemical copolymerization of o-phenylenediamine and o-aminophenol, and complementary sites were formed after the copolymer was electrochemically reduced in ammonium aq...

A brush-like block copolymer of poly(acrylic acid)-block-poly(oligo(ethylene glycol)methyl ether acrylate) (PAA-b-POEGA) was synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization, and its dispersing ability as polymeric dispersant for graphene oxide (GO) sheets in aqueous suspensions was studied in comparison with a traditional random copolymer having similar ch...