The target pyrrolyl-thiazoldin-4-one inhibitor (PEHT) was synthesized by the cyclization of 2-acetylpyrrole thiosemicarbazone with ethyl bromoacetate, and its chemical structure determined different spectroscopic techniques, such as FT-IR, 1H NMR, 13C NMR. PEHT performance, a mild steel (MS) corrosion inhibitor, in an acidic solution evaluated mass loss (ML), potentiodynamic polarization (PDP),...

Electrochemical dissolution of metallic copper into slightly acidic aqueous solutions of chitosan yields a clear and stable dispersion of Copper Oxide nanoparticles into the organic polymer host. The electrochemically synthesized chitosan:CuOx nanocomposite is characterized by means of spectrophotometry, frequency domain electrical measurements and morphological analysis. Solid state electroche...

Electrochemical investigations of 1,2,4-triazole and benzotriazole in aqueous acidic media has been carried out by cyclic voltammetric measurements. Cyclic voltammetric experiments were carried on glassy carbon (GC) working electrode. Effect of potential scan rate, pH of the solution and use of different surfactant on the electrochemical behavior has been investigated. Single reduction wave was...

The aim of the present study is to analyze the electrochemical behavior of five different dental alloys: two cobalt-chromium alloys (CoCr and CoCr-c), one nickel-chromium-titanium alloy (NiCrTi), one gold-palladium alloy (Au), and one titanium alloy (Ti6Al4V), and the galvanic effect when they are coupled to titanium implants (TiG2). It was carried out by electrochemical techniques (open circui...

In this paper, the electrochemical behaviour of passive films formed on AISI 321 stainless steel (AISI 321) immersed in 0.1 M NaOH + 0.1 M KOH solution was evaluated by different electrochemical techniques. For this purpose, passive films were formed at open circuit potential for 1 to 12 hours and then electrochemical measurements were done. The polarization curves suggested that AISI 321 showe...

Concentrated sulfuric acid (SA) and nonionic surfactant (C12H25(OCH2CH2)10OH, C12E10) form lyotropic liquid crystalline (LLC) mesophases in a broad range of SA concentrations; the SA/C12E10 mole ratio may vary from 2 to 11 in the LLC mesophases in the presence of a small amount of water. The mesophase is hexagonal at low SA concentration and cubic at higher concentrations. Three different compo...

A new approach of improving drug dissolution properties is described. This method exploits the property of a carrier owing to the hydrotalcite-type anionic clays (HTlc). HTlc is an inorganic layered solid that lodges anionic compounds among its layers. As HTlc dissolves at acidic pH values (pH < 4), the anions intercalated among the layers are promptly released in the medium. In this article so...

In the present study we performed anodization of stainless steel AISI 316L varying voltage, time and H 2 O concentration in electrolyte obtaining self-ordered porous oxides. Open-circuit potential measurements, potentiodynamic polarization electrochemical impedance spectroscopy were 0.1 M SO 4 , NaCl NaOH electrolytes. The metallic substrate underneath grown oxide was also characterized. result...