Electroosmotic flow within capillary zone electrophoresis can be altered electronically through a mechanism modeled as surface conductance. Experimentally, a small zone of conductive silver on the outer surface of the capillary is shown to permit good control of electroosmotic flow with an applied external voltage. This control is modeled as capacitance across the capillary wall and conductance...

Abstract. We derive a mathematical model of a nematic electrolyte based on the Leslie-Ericksen theory of liquid crystal flow. Our goal is to investigate the nonlinear electrokinetic effects that occur because the nematic matrix is anisotropic, in particular, transport of ions in a direction perpendicular to the electric field as well as quadratic dependence of the induced flow velocity on the e...

The control of electroosmotic flow by electronic means for capillary zone electrophoresis is presented. This is accomplished by the application of a radial voltage field with a rugged and flexible conductive polymer sheath. Fundamental theory for effect of the applied radial voltage on electroosmotic flow is developed. In addition, the effects of surface pretreatments are examined and compared ...

Due to the increasingly wide application of electroosmotic flow in micromachines, this paper investigates the electroosmotic flow of the power-law fluid under high zeta potential in a cylindrical microcapillary for different dimensionless parameters. The electric potential distribution inside a cylindrical microcapillary is presented by the complete Poisson-Boltzmann equation applicable to an a...

Homogeneous and rapid mixing in microfluidic devices is difficult to accomplish, owing to the low Reynolds number associated with most flows in microfluidic channels. Here, an efficient electroosmotic micromixer based on a carefully designed lateral structure is demonstrated. The electroosmotic flow in this mixer with an asymmetrical structure induces enhanced disturbance in the micro channel, ...

We have developed electroosmotic pumps (EOPs) fabricated from 15-nm-thick porous nanocrystalline silicon (pnc-Si) membranes. Ultrathin pnc-Si membranes enable high electroosmotic flow per unit voltage. We demonstrate that electroosmosis theory compares well with the observed pnc-Si flow rates. We attribute the high flow rates to high electrical fields present across the 15-nm span of the membra...

Effects of ionic concentration gradient on electroosmotic flow (EOF) mixing of one stream of a high concentration electrolyte solution with a stream of a low concentration electrolyte solution in a microchannel are investigated numerically. The concentration field, flow field and electric field are strongly coupled via concentration dependent zeta potential, dielectric constant and electric con...

Electroosmotic pumps employing silica frits synthesized from potassium silicate as a stationary phase show strong electroosmotic flow velocity and resistance to pressure-driven flow. We characterize these pumps and measure an electroosmotic mobility of 2.5 × 10(-8) m(2)/V s and hydrodynamic resistance per unit length of 70 × 10(17) Pa s/m(4) with a standard deviation of less than 2% even when v...