An attempt was made to study the bioactive compounds from a terrestrial Streptomyces sp. ANU 6277 isolated from laterite soil. Four active fractions were recovered from the solvent extracts obtained from the culture broth of five day-old strain. Three bioactive compounds were purified and identified as 3-phenylpropionic acid, anthracene-9,10-quinone and 8-hydroxyquinoline. The components of the...

7-Hydroxycoumarine undergoes a smooth reaction with alkyl propiolates in the presence of triphenylphosphine (15 mol%) to produce the corresponding alkyl (E)-3-((2-oxo-2H-chromen- 7-yl)oxy)acrylate in good yields. When the reaction was performed by 3-hydroxyquinoline similar alkyl acrylates were obtained.

5- hydroxyisoquinoline undergoes a smooth reaction with alkyl propiolates in the presence of triphenylphosphine (15 mol%) to produce the corresponding (E)-alkyl 3-(isoquinolin-5-yloxy) acrylate in good yields. When the reaction was performed by 2-methyl 4-hydroxyquinoline and 3-nitro 4-hydroxypyridine, similar aryl vinyl ethers were obtained.

A series of manganese(I) tricarbonyl complexes formulated as [Mn(8-HQ)(CO)3Imd] (HQ = hydroxyquinoline and Imd imidazole derivatives) was synthesized fully characterized. These structures could be easily accessed from a common dimeric edifice [Mn2(8-HQ)2(CO)6]. The structure this complex has been confirmed by X-ray diffraction studies. Its reaction with range derivatives (Imd) yielded the monom...

Five new tetranuclear complexes based on an 8-hydroxyquinoline Schiff base derivative and the β-diketone coligand, [Ln4(acac)4L6(μ3-OH)2]·CH3CN·0.5CH2Cl2 (Ln = Gd (1), Tb (2), Dy (3), Ho (4) and Er (5); HL = 5-(benzylidene)amino-8-hydroxyquinoline; acac = acetylacetonate) have been synthesized, and structurally and magnetically characterized. Complexes 1-5 have similar tetranuclear structures. ...

Abstract This study was carried out in the laboratory of Shangqiu Institute Technology, Henan to investigate effect a different combination inorganic salt on quality and physiological characteristics cut flowers (CFs) Perpetual Carnation. Furthermore, find best preservation solution that can enhance ornamental value CFs Carnation prolong its vase life. Sucrose, 8-hydroxyquinoline, paclobutrazol...

To establish whether the use of proteinase inhibitors in the routine determination of in vitro plasma renin activity overestimates the potency of renin inhibitors in vivo, we examined the effects of phenylmethylsulfonyl fluoride and 8-hydroxyquinoline sulfate on the binding to plasma proteins and the respective IC50 values (50% inhibiting concentrations) of three renin inhibitors. All three ren...

The detection of nerve agent simulants is achieved by the photoinduced electron transfer (PET) mechanism. A ‘‘turn-on’’ fluorescence response upon phosphorylation at 8-hydroxyquinoline of norbornene-based triazolyl functionalized 8-hydroxyquinoline (NCHQ) followed by intramolecular rearrangement provides very intense green emission. The detection limit of polymer (PNCHQ) coated paper strips is ...

The water soluble tris-aqua complex [Gd(dhqN-SO3)(H2O)3](3-) based on a hexadentate hydroxyquinoline ligand shows high thermodynamic stability and high relaxivity (12.54 mM(-1) s(-1) at 1.2 T). Its non-covalent confinement in 25 nm silica nanoparticles prevents transmetallation and endogenous anion binding and leads to higher relaxivity over a wide range of magnetic fields.

In vivo incorporation of a series organometallic photoluminescent complexes in Phaeodactylum tricornutum diatom shells (frustules) is investigated as biotechnological route to luminescent biosilica nanostructures. [Ir(ppy)2bpy]+[PF6]−, [(2,2′-bipyridine)bis(2-phenylpyridinato)iridium(III) hexafluorophosphate], [Ru(bpy)3]2+ 2[PF6]−, [tris(2,2′-bipyridine)ruthenium(II) AlQ3 (tris-(8-hydroxyquinol...