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Multipath error is considered one of the major errors affecting GPS observations. One can benefit from the repetition of satellite geometry approximately every sidereal day, and apply filtering to help minimize this error. For GPS data at 1 second interval processed using a double-difference strategy, using the day-to-day coordinate or phase residual autocorrelation determined with a 10 hour wi...
Interactions of 5,10,15,20-Tetrakis(N-propylpyridinium-4-yl)-21H,23H-porphyrin (TPrPyP4) with dimer hairpin (G4T4G4)2 and parallel four-stranded (TG4T)4 G-quadruplex DNAs in Na+-containing buffer were studied. The results show that two TPrPyP4 molecules bind to both G-quadruplexes by a noncooperative and nonequivalent binding mode, and there are one high affinity site and one low affinity site,...
Triplet–triplet annihilation photon upconversion (TTA-UC) of an organic molecular dye pair, 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyrin platinum(II) (PtOEP) and 1,3,6,8-tetraphenylpyrene (TPPy), has been studied in a wide range green solvents (alcohols, esters, carbonates, ketones, aromatics, ethers, dipolar aprotic). UC is important for the study energy-transfer reactions where solvent pla...
Two-component self-assembly supramolecular coordination complexes with particular photo-physical property, wherein unique donors are combined with a single metal acceptor, can be utilized for many applications including in photo-devices. In this communication, we described the synthesis and characterization of two-component self-assembly supramolecular coordination complexes (SCCs) bearing tria...
A simple and compact system was developed for the on-site analysis of lead in environmental water samples. The system consisted of a custom-made blue diode as a light source, a liquid core waveguide (LCW) as spectrophotometric cell and a compact UV-visible spectrometer. It weighed within 1.5 kg in total. Lead was detected using a spectrophotometric indicator reagent (TPPS: 5,10,15,20-tetrapheny...
Derivatives of chlorophyl, e.g. Fe-chlorin e6-Na, alpha, beta, gamma, delta-Tetraphenylporphine-tetrasulfonic acid disulfonic acid salt tetrahydrate (Fe-TPPTS) and alpha, beta, gamma, delta-Tetrakis (4-N-trimethylaminophenyl) porphine, tetra (p-toluensulfonate (Fe-TTMAPP), express SOD mimicking activity. Examination was made of suppressive effects of human cancer cell lines by derivatives of ch...
The origin of electrophosphorescence from a doped polymer light emitting diode ~LED! has been investigated. A luminescent polymer host, poly~9,9-dioctylfluorene! ~PFO!, was doped with a red phosphorescent dye, 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyrin platinum~II! ~PtOEP!. The maximum external quantum efficiency of 3.5% was obtained at a concentration of 4% PtOEP by weight. Energy transfe...
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