The isolated activation segment of pig procarboxypeptidase A binds two Tb3+ ions in a strong and specific way. In contrast, the binding of Ca2+, Cd2+ and Mg2+ is weak. The binding of Tb3+ increases the resistance of the isolated activation segment against proteolysis and competes for the binding of the carbocyanine dye Stains-All. This dye forms complexes with the activation segment showing spe...

We have previously reported that lanthanides markedly potentiate the GABA-induced chloride current by acting at a distinct site on the GABAA receptor-channel complex (Ma and Narahashi, 1993a,b). These studies have now been extended to the single-channel level and changes in gating kinetics of GABAA receptor currents caused by 100 microM terbium (Tb3+) are reported. The GABA-induced currents wer...

Single crystals of Tb3+ single-doped and Tb3+/Pr3+ co-doped CaYAlO4 were produced by the Czochralski method. The room-temperature polarized absorption spectra, emission decay curves recorded analyzed in detail. cross-section around 487 nm was found to be 1.53 × 10−22 cm2 for π polarization Tb3+:CaYAlO4 crystal increased 5.23 Tb3+/Pr3+:CaYAlO4 crystal. spectroscopic parameters calculated through...

Lanthanide ions act as excellent luminescence centers and good charge carrier traps. By selecting proper lanthanide ions, persistent phosphors with the desired luminescent color can be developed. In addition, an appropriate host material give not only better performance but also additional function. Herein, bright white of Pr3+–Tb3+–Eu3+ tridoped paramagnetic Gd3Ga5O12 (GGG) are successfully Th...

ABSTRACT A simple co-precipitation reaction between Ln3+ cations (Ln = lanthanide) and phosphate ions in the presence of polyethylene glycol (PEG), including post-treatment under hydrothermal conditions, leads to the formation of Tb3+-doped LaPO4 crystalline nanorods. The nanoparticles obtained can be successfully coated with amorphous and porous silica, forming core/shell-type nanorods. Both p...

Lanthanum was previously reported to potentiate the GABA-induced chloride currents reversibly by acting at a distinct site on the GABAA receptor-channel complex (Ma and Narahashi, 1993). We now report that all other lanthanides tested enhanced the GABA responses with greater efficiencies and produced inward currents by themselves. The rank order of efficacies of lanthanides to potentiate the GA...

Herein, we show that the substitution of Sr2+ by trivalent lanthanide ions (Lu3+, La3+, Tb3+) in SrTiO3 nanocrystals stabilizes and enhances Ti3+ near-infrared emission (around 800 nm). This occurs from 6-fold coordinated luminescent centers appear vacancy–Ti3+–O form after doping into site. The strong dependence on temperature provided means for tailored chemical engineering nanonthermometers ...

Objective(s):Cefixime (Cfx), is a semi-synthetic third-generation oral cephalosporin antibiotic that is prescribed for the treatment of susceptible infections. There are some procedures for the determination of Cfx in pharmaceutical formulations and biological samples. Herein a spectrofluorimetric method was proposed for Cfx determination based on the fluorescence quenching of terbium-danofloxa...

Rapid, multiplexed, sensitive and specific identification and quantitative detection of nitric oxide (NO) are in great demand in biomedical science. Herein, a novel multifunctional probe based on the intramolecular LRET (luminescence resonance energy transfer) strategy, TRP-NO, was designed for the highly sensitive and selective ratiometric and luminescence lifetime detection of lysosomal NO. B...