The transformation characterization of Ni(OH)2/NiOOH in Ni-Pt films was investigated using an electrochemical quartz crystal microbalance (EQCM) in an alkaline electrolyte under various experiment conditions. The Ni-Pt films were prepared by electro-deposition on gold-coated quartz crystal chips. When cyclic voltammetry (CV) was performed continually, the OH ions diffused into the Ni-Pt film to...

in this paper, the electrochemical hydrogen storage in nanocomposite materials was studied. multi-walled carbon nanotubes (mwcnts) electrode was prepared by mixing with special composite. the optimum ratio of mwcnts was estimated 30-70% (w/w) in the composite material. mwcnts were synthesized by chemical vapor deposition (cvd). the nanocomposite was homogenized by microwave. cyclic voltammetry ...

In this paper, the effect of Ni on the formation of Cu6Sn5 and Cu3Sn intermetallics between tin and (Cu,Ni)-substrates has been studied by making use of the thermodynamic assessment of the Sn-Cu-Ni system. The driving forces for the diffusion of the elements in the intermetallic layers were calculated as a function of Ni-content. Assuming constant mobilities of component atoms, the results sugg...

Mesoporous Ni–alumina catalysts (Ni–alumina-pre and Ni–alumina-post) were synthesized by one-step sol–gel method using micelle complex comprising lauric acid and nickel ion as a template with metal source and using aluminum sec-butoxide as an aluminum source. The Ni–alumina catalysts showed relatively high surface areas (303 m/g for Ni–alumina-pre and 331 m/g for Ni–alumina-post) and narrow por...

We present a natural extension of Andrews’ multiple sums counting partitions of the form (λ1, · · · , λm) with λi ≥ λi+k−1 + 2. The multiple sum that we construct is the generating function for the so-called K-restricted jagged partitions. A jagged partition is a sequence of non-negative integers (n1, n2, · · · , nm) with nm ≥ 1 subject to the weakly decreasing conditions ni ≥ ni+1− 1 and ni ≥ ...

The impact of shifts in the spectral quality of light on morphogenesis, flowering, and photoperiodic gene expression during exposure to light quality of night interruption (NI) was investigated in Dendranthema grandiflorum. The circadian rhythms of plants grown in a closed walk-in growth chamber were interrupted at night for a total of 4 h, using light-emitting diodes with an intensity of 10 μm...

A dinuclear nickel complex with methyl and thiolate ligands, Ni(dadt(Et))Ni(Me)(SDmp) (2), has been synthesized as a dinuclear Ni(d)-Ni(p)-site model of acetyl-CoA synthase (ACS) (dadt(Et) is N,N'-diethyl-3,7-diazanonane-1,9-dithiolate; Dmp is 2,6-dimesitylphenyl). Complex 2 was prepared via 2 methods: (i) ligand substitution of a dinuclear Ni(II)-Ni(II) cation complex [Ni(dadt(Et)) Ni(tmtu)2] ...

The transport of nickel (Ni) across the renal brush border membrane of the rainbow trout was examined in vitro using brush border membrane vesicles (BBMVs). Both transmembrane transport of Ni into an osmotically active intravesicular space, and binding of Ni to the brush border membrane itself, were confirmed. Nickel (Ni) uptake fitted a two component kinetic model. Saturable, temperature-depen...

Insects can vary greatly in whole-body elemental concentrations. Recent investigations of insects associated with Ni hyperaccumulator plants have identified insects with relatively elevated whole-body Ni levels. Evaluation of the limited data available indicates that a whole-body Ni concentration of 500 g Ni/g is exceptional: I propose that an insect species with a mean value of 500 g Ni/g or g...