Supramolecular Polymers with Orthogonal Functionality Report Title Supramolecular polymers with orthogonal interactions are of broad interest, and reports on such materials with multifunctional stimuli-responsive behavior are rare. Polymer blends based on a poly(ethylene-co-butylene) core (PEB) terminated with either 2-ureido-4[1H]-pyrimidinone (UPy) hydrogen-bonding motifs (UPy-PEB-UPy) or 2,6...

The paper is focusses on the study of the thermal and mechanical behaviour of reinforced agro-materials. Various formulations based on plasticized starch matrix have been carried out, varying matrix formulation, filler content, fibres length and nature. Cellulose and lignocellulose fibres, which show unequal surface tensions, have been tested. After extrusion and injection moulding, the propert...

Plant-herbivore interactions are hypothesized to drive vole population cycles through the grazing-induced production of phytoliths in leaves. Phytoliths act as mechanical defences because they deter herbivory and lower growth rates in mammals. However, how phytoliths impair herbivore performance is still unknown. Here, we tested whether the amount of phytoliths changes tooth wear patterns. If c...

The objective of the current study was to determine the in vitro passive transverse mechanical properties of skeletal muscle with Dynamic Mechanical Thermal Analysis (DMTA) tests. The starting hypotheses was that the time-temperature-superposition principle could be used to expand the DMTA results to a 1 kHz frequency range. Experiments were performed with rat hind leg skeletal muscle tissue sa...

Epoxy – Polysulfide copolymers without or with low amounts of epoxy in their structure have poor mechanical properties in oxidative curing system.To strengthen the mechanical properties of polysulfide elastomer inclusion of epoxy resin (Epon828) as hard segment was studied. FT-IR spectroscopy and rheometry were used to verify the formation of epoxy-polysulfide copolymer.  Results obtained f...

This work focuses on the reinforcement of polyoxymethylene (POM) by nanosilica particles (NS) in order to increase flexural strength and hardness POM matrix. Thermo - mechanical properties POM/NS nanocomposite were investigated using dynamic thermal analysis (DMTA).

Nanocomposites of encapsulated silica nanoparticles were prepared by in situ emulsion polymerization of acrylate monomers. The synthesized material showed good uniformity and dispersion of the inorganic components in the base polymer, which enhances the properties of the nanocomposite material. A nonionic surfactant with lower critical solution temperature (LCST) was used to encapsulate the sil...

By means of dynamic mechanical thermal analysis (DMTA), selected tropical wood species, namely Eugenia spp., Artocarpus rigidus, Artocarpus elesticus, Koompassia malaccensis, and Xylopia spp. have been characterized. The woods were treated with sodium meta-periodate to convert them into wood polymer composites (WPC). After two weeks the WPC were chemically treated with phenylhydrazine to conver...

A novel class of polymers called "slide-ring" (SR) materials with slideable junctions were used for high damping composites for the first time. The SR acts as the high damping phase dispersed in the natural rubber (NR) matrix, and epoxidized natural rubber (ENR) acts as the compatibilizer. The morphological, structural, and mechanical properties of the composites were investigated by atomic for...