نتایج جستجو برای: α diketones

تعداد نتایج: 165488  

Journal: :Bulletin of the Chemical Society of Japan 1967

2014
Michael E. Jung Gang Deng

Both alkylarylalkynes and diarylalkynes 1 are converted into the α-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do not provide the diketone product. A possible mechanism is proposed.

Journal: :Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 2015
Minoru Yamaji Yurie Suwa Rieko Shimokawa Cecilia Paris Miguel Ángel Miranda

Photochemical processes of 4-tert-butyl-4'-methoxydibenzoylmethane (Avobenzone, AB), 4-phenylbenzoylbenzoyl-, 4-phenylbenzoyl-2'-furanyl- and 4-phenylbenzoyl-2'-thenoylmethanes (PB@Ph, PB@F and PB@T, respectively) substituted with Br and Cl at the C2 position were studied by stationary and laser flash photolyses in solution. The absorption spectral features showed that the molecular structures ...

Journal: :Organic & biomolecular chemistry 2012
Valerio Bertolasi Olga Bortolini Adelaide Donvito Giancarlo Fantin Marco Fogagnolo Pier Paolo Giovannini Alessandro Massi Salvatore Pacifico

Diaryl α-diketones do not undergo polarity reversal in the presence of (benzo)thiazolium carbenes but are engaged in a novel multicomponent reaction with water to efficiently give medicinally relevant 1,4-thiazin-3-one heterocycles. Three different sets of conditions have been optimized to furnish the title compounds in fair to excellent yields depending on the electronic properties of α-diketo...

Journal: :nanochemistry research 1999
mostafa karimkoshteh marziyeh bagheri behzad zeynizadeha

various aldoximes and ketoximes synthesis of corresponding aldehydes and ketones in the presence of sio2@feso4 nano composite as recoverable nano catalyst and nh2oh·hcl. the sio2@feso4 nano composite system was carried out between 10 to 15 min in oil bath (70-80 °c) under solvent-free condition in excellent yields in addition this protocol can be used for industrial scales. this method offers s...

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