The product distribution of methanol to hydrocarbons conversion over SAPO-34 and ZSM-5 catalysts was studied using thermodynamic equilibrium and Anderson-Schulz-Flory (ASF) distributions. The equilibrium compositions were calculated using constrained Gibbs free energy minimization. The effect of catalyst type was considered by setting upper limits to product carbon number due to sh...

We report synthetic protocols and guiding principles inspired by mechanistic considerations for the synthesis of crystalline microporous solids via interzeolite transformations that avoid direct intervention by organic structure-directing agents. These protocols are specifically implemented to synthesize highsilica MFI (ZSM-5), CHA (chabazite), STF (SSZ-35), and MTW (ZSM-12) zeolites from FAU (...

Neutron scattering methods observed complete room temperature conversion of methanol to framework methoxy in a commercial sample of methanol-to-hydrocarbons (MTH) catalyst H-ZSM-5, evidenced by methanol immobility and vibrational spectra matched by ab initio calculations. No methoxylation was observed in a commercial HY sample, attributed to the dealumination involved in high silica HY synthesis.

Kinetic Analysis of the Decomposition of Nitrous Oxide over ZSM-5 Catalysts Freek Kapteijn, Gregorio Marbán,∗ José Rodriguez-Mirasol,† and Jacob A. Moulijn Industrial Catalysis, Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands; ∗Instituto Nacional del Carbon, Oviedo, Spain; and †Department of Chemical Engineering, University of ...

A novel route is proposed for the preparation of mesopore containing zeolite ZSM-5 via in situ hydrothermal treatment of a solution containing alkali-dissolved SBA-15 containing carbonized surfactant P123 in the mesopores; it exhibited prominent stability enhancement for methanol to propylene reaction.

This study aimed to valorize microcrystalline cellulose (MCC) using protonated zeolite catalysts such as (H-ZSM-5) and Cr/H-ZSM-5 (5%) in ionic liquid. The catalytic effect synergy with 1-butyl-3-methylimidazolium Chloride ([BMIM] Cl) liquid was studied detail. total reducing sugar (TRS) determined the 3, 5-dinitrisalcylic acid (DNS) array method. were characterized techniques Fourier transform...

lamno3 and lamno3/zsm-5 nano catalysts were synthesized by pechini method and their physical-chemical properties were characterized using xrd, ftir, sem-edx, uv-vis drs, bet surface area and tpr. the correlation between characteristic properties and activity of catalysts were investigated. the catalytic performance of the catalysts was evaluated in combustion of 2-propanol and compared with 1% ...