The catalyst Pt(1 wt %)/Ce(0.6)Zr(0.4)O(2) is studied by CO-temperature programmed reduction (CO-TPR), isothermal oxygen storage complete capacity (OSCC), X-ray absorption spectroscopy (XAS) at the Pt L(III) edge, and in situ X-ray diffraction (in situ XRD), with the aim of elucidating the role of supported metal in CO oxidation by ceria-based three-way catalysts (TWC). The redox behavior of Pt...

This review introduces concepts and background from the ceramics engineering literature regarding metastable zirconia ceramics to establish a context for understanding current and emerging zirconia-based dental ceramics.

The hydrogen solubility in zirconia (yttria stabilized zirconia, YSZ) using a tritium imaging plate (IP) technique has been measured in a temperature region ranging from 673K to 973K. The tritium distribution in the zirconia specimens was nearly uniform suggesting an equilibrated dissolution. The hydrogen solubility in specimens were rather low (around ppm or below) and showed Arrhenius type te...

STATEMENT OF PROBLEM Successful long-term bonding to zirconia ceramic remains a challenge, requiring special cements and surface roughening by airborne-particle abrasion, which might negatively affect the ceramic. PURPOSE The purpose of this study was to evaluate the shear bond strength (SBS) of composite resin cylinders to a modified zirconia surface using different luting techniques after t...

the aim of this study was to determine the effect of trenched zirconia bar on the von mises stress distribution of ips -empress ii core ceramics.the three-dimensional model including a three-unit bridge from the second premolar to the second molar was designed. the model was reinforced with zirconia bar (zb), zirconia bar with vertical trench (vzb) and zirconia bar with horizontal trench (hzb) ...

STATEMENT OF PROBLEM Zirconia-based restorations have the common technical complication of delamination, or porcelain chipping, from the zirconia core. Thus the shear bond strength between the zirconia core and the veneering porcelain requires investigation in order to facilitate the material's clinical use. PURPOSE The purpose of this study was to evaluate the bonding strength of the porcela...

PURPOSE The aim of this study was to compare osteoblast behavior on zirconia and titanium under conditions cultured with bone morphogenetic protein-2. METHODS MC3T3-E1 cells were cultured on sandblasted zirconia and sandblasted/etched titanium discs. At 24 hours after seeding MC3T3-E1, the demineralized bone matrix (DBM) gel alone and the DBM gel with bone morphogenetic protein-2 (BMP-2) were...

OBJECTIVES To investigate the effect of air-drying pressure during ceramic primer coating on zirconia/resin bonding and the surface characteristics of the primed zirconia. METHODS Two ceramic primers (Clearfil Ceramic Primer, CCP, Kuraray Medical Inc. and Z-Prime Plus, ZPP, Bisco Inc.) were applied on the surface of air-abraded zirconia (Katana zirconia, Noritake) and dried at 4 different air...

Due to its high strength and biocompatibility, the use of zirconia is recently on the rise, but there are difficulties in bonding compared to other conventional ceramic materials. Since it doesn’t contain glass, it cannot be etched by hydrofluoric acid and tribochemical silica coating is not effective. Therefore, unlike conventional materials, the adhesion with luting cement is weak and the res...

Alumina/zirconia (Al2O3/ZrO2) multilayer thin films were deposited on Si (100) substrates at an optimized oxygen partial pressure of 3 Pa at room temperature by pulsed laser deposition. The Al2O3/ZrO2 multilayers of 10:10, 5:10, 5:5, and 4:4 nm with 40 bilayers were deposited alternately in order to stabilize a high-temperature phase of zirconia at room temperature. All these films were charact...