The effect of molecular architecture of a surfactant, particularly the attachment position of benzene sulfonate on the hexadecane backbone, at the decane-water interface was investigated using atomistic MD simulations. We consider a series of surfactant isomers in the family of alkyl benzene sulfonates, denoted by m-C16, indicating a benzene sulfonate group attached to the mth carbon in a hexad...

steel porous plates. Various control options for the tension applied to these porous plates have been advocated. The composition and quantity of leachate as it moves down through The simplest being zero tension, where no capacity to the vadose zone is seldom measured directly because sampling in this unsaturated zone at the depths required has proven to be extremely exert a tension on the plate...

Experimental data on interfacial tension of 42 binary liquid-liquid systems using water, aqueous glycerol, aqueous polymeric solutions of polyvinylpyrrolidone (PVP), poly(ethylene oxide) (PEO), carboxymethyl cellulose (CMC) and polyacrylamide (PAM) as continuous phase, and carbon tetrachloride, chlorobenzene, bromobenzene, nitrobenzene, nitrotoluene and ethyl chloroacetate as dispersed phase at...

Surface tension, the tendency of fluid interfaces to behave elastically and minimize their surface, is routinely calculated as the difference between the lateral and normal components of the pressure or, invoking isotropy in momentum space, of the virial tensor. Here we show that the anisotropy of the kinetic energy tensor close to a liquid-vapor interface can be responsible for a large part of...

A theory is presented to account for the increase in surface tension of water in the presence of electrolyte. Unlike the original “grandcanonical” calculation of Onsager and Samaras, which relied on the Gibbs adsorption isotherm and lead to a result which could only be expressed as an infinite series, our approach is “canonical” and produces an analytic formula for the excess surface tension. F...

The purpose of this article is to clarify the Cauchy theory of the water waves equations as well in terms of regularity indexes for the initial conditions as for the smoothness of the bottom of the domain (namely no regularity assumption is assumed on the bottom). Our main result is that, following the approach developped in [1], after suitable paralinearizations, the system can be arranged int...

Surface tension, gamma, strongly affects interfacial properties in fluids. The degree to which polarizability affects gamma in water is thus far not well established. To address this situation, we carry out molecular dynamics simulations to study the interfacial forces acting on a slab of liquid water surrounded by vacuum using the Gaussian charge polarizable (GCP) model at 298.15 K. The GCP mo...

We study dispersive properties of one-dimensional surface waterwaves under surface tension, based on the formulation of the problem as a nonlinear dispersive equation coupled with a transport-type equation. We establish a dispersion estimate on time scales depending on the size of the frequencies. We infer that, if s is large enough, then a solution u of the dispersive equation satisfies local-...

This paper is concerned with the simulation of periodic traveling deep-water freesurface water waves under the influence of gravity and surface tension in two and three dimensions. A variety of techniques is utilized, including the numerical simulation of a weakly nonlinear model, explicit solutions of low-order perturbation theories, and the direct numerical simulation of the full water wave e...

1327 Soil Sci. Soc. Am. J. 74:1327–1338 Published online 21 May 2010 doi:10.2136/sssaj2009.0360 Mention of trade names does not imply endorsement by the USDA. Received 21 Sept. 2009. *Corresponding author ([email protected]). © Soil Science Society of America, 5585 Guilford Rd., Madison WI 53711 USA All rights reserved. No part of this periodical may be reproduced or transmitted in any form or b...