Nitrogen doped mesoporous TiO(2) was prepared via a modified two-step hydrothermal route. In contrast to undoped mesoporous TiO(2), nitrogen doped mesoporous TiO(2) has superior photocatalytic activity under both UV and visible light irradiation. Photoluminescence spectra reveal that nitrogen doped mesoporous TiO(2) possesses abundant surface states, which can play a vital role in trapping phot...

Nanostructured MnO(2) exhibits a high turnover frequency for oxygen evolution under visible light and high stability in strong acidic conditions.

A dual visible light photoredox and gold-catalysed C(sp(2))-C(sp(2)) cross coupling is described. The success of this mild, oxidant- and base-free cross coupling is highly dependent on the amount of water added. Mechanistic studies show two distinct pathways depending on the gold catalyst employed: transmetallation of the arylboronic acid with gold(i) occurs prior to oxidation of gold(i) to gol...

The highest possible resolution for printed colour images is determined by the diffraction limit of visible light. To achieve this limit, individual colour elements (or pixels) with a pitch of 250 nm are required, translating into printed images at a resolution of ∼100,000 dots per inch (d.p.i.). However, methods for dispensing multiple colourants or fabricating structural colour through plasmo...

the nanostructured anatase tio2 with high thermal stability was prepared by polymeric sol-gel method without any additives. the particle size distribution of polymeric titania sol was determined by dynamic light scattering (dls). then properties of obtained titania were investigated by tg-dta, xrd, fesem and tem. also, the decolorization capability of resultant anatase was evaluated using methy...

A novel copper(II) complex has been developed in which the counter anion, acylphosphinate, serves as a visible light photoinitiator. This molecule is inactive in the dark but, upon visible light exposure, both CuAAC and ATRP reactions are readily and rapidly initiated.

Here, W(NxS1-x)2 nanoflowers were fabricated by simple sintering process. Photocatalytic activity results indicated our fabricated N-doped WS2 nanoflowers shown outstanding photoactivity of degradating of rhodamine B with visible light. Which is attributed to the high separation efficiency of photoinduced electron-hole pairs, the broadening of the valence band (VB), and the narrowing of energy ...

Ultraviolet (UV) radiation affects human life and UV exposure is a significant everyday factor that individuals must be aware of to ensure minimal damaging biological effects to themselves. UV exposure is affected by many complex factors. Albedo is one factor, involving reflection from flat surfaces. Albedo is defined as the ratio of reflected (upwelling) irradiance to incident (downwelling) ir...

New phenothiazine-based organic dyes with two anchoring groups at 3,7 positions and systematic alkyl chains on nitrogen were prepared. Their TiO(2)-Pt composites showed excellent photo-catalytic activities in visible light-induced water splitting. Interestingly, phenothiazine dyes with longer alkyl chains showed better stability in catalytic systems.