The Nazarov cyclization of divinyl ketones gives access to cyclopentenones. Replacing one of the vinyl groups by a cyclopropane leads to a formal homo-Nazarov process for the synthesis of cyclohexenones. In contrast to the Nazarov reaction, the cyclization of vinyl-cyclopropyl ketones is a stepwise process, often requiring harsh conditions. Herein, we describe two different approaches for furth...

Flattened carbon nanotubes (flCNTs) are a promising form of composite material reinforcement because their capacity for self-assembly and packing efficiency, which could ultimately lead to improved thermo-mechanical properties relative current state-of-the-art materials. An important design parameter materials is the choice polymer matrix , as characteristics reinforcement/polymer interface can...

Lactol carbocyclisations provide a succinct method of constructing the oxabicyclo[3.2.1]octane scaffold, motif present in various natural products medicinal interest. Lactols containing an unsaturated ketone or ester were prepared by olefin cross-metathesis; electrophilic alkene derived from methyl vinyl underwent concomitant terminal α-methylenation and oxa-Michael addition to give bridged lac...

Background and Aim: One of the problems of all ceramic restorations is their risk of fracture due to occlusal loads. The aim of the present study was to compare the effect of two marginal designs (shoulder and chamfer) on the fracture resistance of IPS-emax all ceramic restorations. Materials and Methods: One extracted maxillary first premolar received chamfer 50' marginal preparation (0.8 m...

A biodegradable polyester resin was polymerized from N-benzyloxycarbonylL -glutamic acid and ethylene glycol. Rhizopus delemar lipase was used as a biocatalyst for the rupture of ester bonds during the hydrolysis studies. Depolymerization was observed to followa Michaelis–Menten mechanism, with the maximumrate of monomer formation dP/dtmax = 1.12 x 10-8 mol/s and the rate constant Km x 2.03 x 1...

Self-healing chemistry used for damage repair have not previously been demonstrated for free-radical polymerization pathways. However, this chemistry is important for addition polymers such as poly(methyl methacrylate) used in bone cement and epoxy vinyl ester used in dental resins. Self-healing biomaterials offer the potential for safer and longer lasting implants and restoratives by slowing o...

−− Two different water-borne dispersions (latex) containing different amounts of vinyl acetate and a commercial vinyl ester monomer (VeoVa10) were evaluated by incorporating them in paint formulations for wall protection. Three paint formulations were prepared with different PVC values. The main properties such as hiding power, washability, tension of adhesion, and elasticity were assessed. Cha...

This study evaluated the microhardness and Young's modulus of a photocurable bonding resin, Clearfil SE Bond (SE), cured with four curing units at different distances. The curing units used were: Candelux (Quartz-tungsten halogen), Lux-O-Max (Blue light emitting diode), Arc-light (Plasma-arc), and Rayblaze (Metal halide). Discs of bonding resin were prepared using vinyl molds and were photocure...