The electrochemical oxidation and reduction of decamethylferrocene is demonstrated in supercritical carbon dioxide at a macro gold disc electrode at 100 bar and 313 K. Fast mass transport effects were exhibited and the corresponding steady-state voltammetry was observed at high scan rates. A highly lipophilic room temperature ionic liquid that readily dissolved in supercritical CO(2) with aceto...

Chebulagic acid is a hydrolyzable tannin found in the fruits of Terminalia bellirica and has been extensively used traditional Indian medicine. Currently, most chebulagic extracted from chebula lesser extent, T. bellirica. Crude extracts these are usually using Soxhlet extraction or reflux methods before purification column chromatography High-Performance Liquid Chromatography (HPLC). We examin...

There are a number of systems in which supercritical cryogenic fluids are used as coolants or propellant fluids. In some modern military aircraft, the fuel is pressurized above its critical point and used as a coolant to remove heat from the aircraft engine. Accurate prediction of heat transfer coefficients to turbulent flows of supercritical fluids is essential in design of such systems. One o...

This study aimed to examine the effectiveness of combined microwave-ultrasonic pasteurization system on Escherichia coli and vitamin C content in sour cherry juice (SCJ). Based on the findings, microwave output power, ultrasound power, and ultrasonic exposure time as well as the microwave-induced temperature were the most effective factors in reducing E. coli and vitamin C content. In addition,...

There are many difficulties in the purification of raw components and products. However, researchers are seeking better ways for purification. One of the recent methods is extraction using supercritical fluids. In this study, the phase equilibria of benzoic acid -supercritical carbon dioxide system were investigated. Regarding the phase equilibria of this system, the modeling of solid-supercrit...

Abstract To increase the effectiveness of coffee oil processing process in drying beans, this study, pretreatment using a microwave was evaluated. The method carried out with three power inputs. After process, it followed by roasting and grinding beans. Then beans were extracted so that obtained. From 3 variations input power, namely MH, MM, ML, from initial moisture content 56.75%, 7.29% row; ...

Numerical studies have been carried out to investigate flow instabilities in a natural circulation loop with supercritical CO2. For steady-state and dynamic analyses of the loop under supercritical conditions, a single-channel, one-dimensional model is developed. In this model, equations for the conservation of mass, momentum and energy are discretized using an implicit finite difference scheme...

Earlier surveys indicate that meat, fish and dairy products are the principal source of polychlorinated dibenzo-p-dioxin (PCDD) exposure in the diet. A recent finding by others of PCDDs in chickens that consumed a feed containing PCDD led to the finding of ball clay, an anti-caking agent, as the source. Supercritical fluid extraction (SFE) was studied as a means to isolate PCDDs from commercial...