نتایج جستجو برای: thiosemicarbazones

تعداد نتایج: 522  

Journal: :Dalton transactions 2011
Arghya Basu Gopal Das

A weakly fluorescent thiosemicabazone (L(1)H) was found to be a selective optical and "turn-on" fluorescent chemodosimeter for Cu(2+) ion in aqueous medium. A significant fluorescence enhancement along with change in color was only observed for Cu(2+) ion; among the other tested metal ions (viz. Na(+), K(+), Mg(2+), Ca(2+), Cr(3+), Zn(2+), Cd(2+), Hg(2+), Pb(2+), Ag(+), Ni(2+), Co(2+), Fe(3+) a...

2016
Daniel Admasu Desam Nagarjuna Reddy Kebede Nigussie Mekonnen

Two selective and sensitive reagents, 2-acetylpyridine thiosemicarbazone (2-APT) and 3-acetylpyridine thiosemicarbazone (3-APT) were used for the spectrophotometric determination of Cu(II). Both reagents gave yellowish Cu(II) complex at a pH range of 8.0-10.0. Beer's law was obeyed for Cu(II)-2-APT and Cu(II)-3-APT in the concentration range of 0.16-1.3 and 0.44-1.05 µg/mL, respectively. The mo...

Journal: :Dalton transactions 2009
Rosa Pedrido María J Romero Manuel R Bermejo Miguel Martínez-Calvo Ana M González-Noya Guillermo Zaragoza

The coordinative chemistry of the tridentate thiosemicarbazone ligand 2-pyridinecarboxaldehyde 4-N-ethylthiosemicarbazone (HL(Et)) has been explored by using an electrochemical methodology. All the complexes have been characterized using analytical and spectroscopic techniques. In the case of copper we have isolated two different complexes, with Cu(L(Et))(2).4H(2)O (6) and [Cu(2)(L(Et))(2)(SO(4...

2014
Maciej Serda Danuta S. Kalinowski Nathalie Rasko Eliška Potůčková Anna Mrozek-Wilczkiewicz Robert Musiol Jan G. Małecki Mieczysław Sajewicz Alicja Ratuszna Angelika Muchowicz Jakub Gołąb Tomáš Šimůnek Des R. Richardson Jaroslaw Polanski Ashley I. Bush

Thiosemicarbazones (TSCs) are an interesting class of ligands that show a diverse range of biological activity, including anti-fungal, anti-viral and anti-cancer effects. Our previous studies have demonstrated the potent in vivo anti-tumor activity of novel TSCs and their ability to overcome resistance to clinically used chemotherapeutics. In the current study, 35 novel TSCs of 6 different clas...

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