Anion exchange polystyrene nanofiber materials (AE) were prepared by electrospinning followed by two-step functionalization of the nanofiber surface by chlorosulfonic acid and ethylendiamine. The photoactive character of these materials was introduced through adsorption of the tetra-anionic 5,10,15,20-tetrakis-(4-sulfonatophenyl)porphyrin photosensitizer (TPPS-AE) on the nanofiber surface or by...

Micrometer-scale monodisperse droplets are produced to generate nanowalled supramolecular microcapsules using microfluidics for high reproducibility and high-throughput manipulation, efficient material consumption, control over hierarchical structure, shape, size. In this study, an optimized microfluidic droplet generation technique a unique liquid–liquid interfacial polymerization method were ...

In the present study, we describe synthesis and characterization of a new covalent organic framework (COF-TPP-CB[6]) which was assembled together by clicking perpropargyloxy cucurbit[6]uril (CB[6]) to azido-functionalized tetraphenylporphyrin (TPP-4N3) through copper-catalyzed azide–alkyne cycloaddition reaction (CuAAC). Perpropargyloxy CB[6] synthesized direct oxidation afford perhydroxy follo...

Actinide-based metal–organic complexes and coordination architectures encompass intriguing properties functionalities but are still largely unexplored on surfaces. We introduce the in situ synthesis of actinide tetrapyrrole under ultrahigh-vacuum conditions, both a metallic support 2D material. Specifically, exposure tetraphenylporphyrin (TPP) multilayer to an elemental beam thorium followed by...