A facile and efficient one-pot three-step process for the synthesis of 5-acetyl-2-imino-4-methylthiazoles via the cyclocondensation of 3-thiocyanatoacetylacetone with various hydrazine or hydrazide derivatives in EtOH has been developed. 3-Thiocyanatoacetylacetone itself has been synthesized as the intermediate from substitution reaction of thiocyanate with 3-chloroacetylacetone. B...

The anodic substitution reaction proceeded smoothly without affecting the oxidation of the nucleophile in a one-step electrochemical operation using acoustic emulsification.

On a regular tetrahedron in spherical space there exist the finite number of simple closed geodesics. For any pair coprime integers $(p,q)$ it was found numbers $\alpha_1$ and $\alpha_2$ depending on $p$, $q$ satisfying inequalities $\pi/3< \alpha_1 < \alpha_2 2\pi/3$ such that with faces angle $\alpha \in \left( \pi/3, \right)$ exists unique, up to rigid motion tetrahedron, geodesic type $(p,q...

The microstructure constitutes one of the pillars materials tetrahedron [...]

An efficient iron-promoted alkylation of indoles with enamides has been accomplished under mild reaction conditions. The reaction proceeded with remarkable regioselectivity leading exclusively to substitution by indoles at α-position of enamides.

We present a succinct way of obtaining all possible higher dimensional generalization of Quantum Yang-Baxter Equation (QYBE). Using the scheme, we could generate the two popular three-simplex equations, namely: Zamolodchikov’s tetrahedron equation (ZTE) and Frenkel and Moore equation (FME). E-mail address: [email protected] E-mail address: [email protected] The Quantum Yang-Baxter Equation (Q...

A highly convergent, stereocontrolled total synthesis of the potent antiproliferative agent (+)phorboxazole A (1) has been achieved. Highlights of the synthesis include: modified Petasis-Ferrier rearrangements for assembly of both the C(11-15) and C(22-26) cis-tetrahydropyran rings; extension of the Julia olefination to the synthesis of enol ethers; the design, synthesis, and application of a n...