Nanocomposite plastics are a promising class of materials with a range of applications, particularly in the automotive industry. By incorporating mineral material of nanoscale dimensions, the mechanical properties of the bulk plastic, such as strength, thermal stability, and flame retardance, are drastically improved, with little to no impact on other favorable properties such as low weight. In...

Thc sterilizing effect of supercritical carben dioxide (SC-CO,) is described as compared with gaseous C02(G-CO,) and liquid CO,(L-CO,). Baker's yeast, ltscherichia eoli, Staphylococcus aure us and eonidia'ofAspergiilus niger were sterilized by treating with SC-CO, at 200 atm and 350C when the water contcnt of each microorganism was 70 .90%, However, dry cells with a water content of 2 .1O% coul...

Chokeberry (Aronia melanocarpa (Michx.) Elliot) is a fruit with exceptionally high levels of phenolic compounds which are accumulated mainly in the peel; hence, the majority remains in the leftovers after juice production. Extraction with the use of carbon dioxide in supercritical conditions was used to isolate phenolic compounds from the pomace. The effect of the process parameters (temperatur...

A cobalt catalyst (25%Co/γ-Al2O3, prepared by slurry phase impregnation) was used in a fixed bed reactor under a pressure/density tuned supercritical fluid mixture of n-pentane/nhexane. By using an inert gas as a balancing gas to maintain a constant pressure, the density of the supercritical fluid could be tuned near the supercritical point while maintaining constant space velocity within the r...

black nightshade is a weed plant that grows abundantly in most parts of iran. in this study, central composite response surface method to investigate the effect of temperature 35-55 °c and pressures 170-350 bar during the dynamic time of 120 min, the particle size of 150 microns and flow rate of 3 liters per minute on the efficiency of oil extracted from the fruits of black nightshade and optim...

Synthesis of poly(2,2,2-trifluoroethyl methacrylate) by supported ATRP was investigated in supercritical carbon dioxide using a copper salt ligated to a polymeric ligand immobilised onto silica; after polymerisation, fluorinated polymers with well defined molecular weight and low polydispersity were obtained.

Heterogeneous esterification of 2-ethyl-1-hexanol and 2-ethyl hexanoic acid using AMBERLYST 15 as solid acid-catalyst in supercritical carbon dioxide (SC-CO2) has been studied. Effect of pressure (150, 200, and 250 bar), temperature (75, 110, and 140 C), flow rate of liquid CO2 (0.4, 0.6, and 0.8 mL.min), type of sample collection, and mole ratio of alcohol to acid (2:1, 1:1, and 1:2) on ester ...

The present study investigates the potential conversion of sugarcane into ethanol and synthetic natural gas. The considered conversion path consists in combining ethanol first and second generation ethanol production plant with a catalytic supercritical water gasification system. The main steps of the ethanol conversion consider fermentation of sugars (1G) and enzymatic hydrolysis of bagasse (2...

New types of Lewis acids as water-stable catalysts have been developed. Metal salts such as rare earth metal triflates can be used in carbon–carbon bond-forming reactions in aqueous media. These salts can be recovered after the reactions and reused. Furthermore, Lewis acid–surfactant-combined catalysts, which can be used for reactions in water without using any organic solvents, have been also ...

Extracting volatile compounds using supercritical carbon dioxide (scCO2) is one of the most interesting applications of supercritical technology, due to the high solubility of these substances in scCO2. Supercritical carbon dioxide extraction (SFE-CO2) has been applied for obtaining extracts from several vegetable matrices, among them turmeric (Curcuma longa), because its volatile oil contains ...