This work aimed to the study effect of ethanol ratios on acidity constants bromocresol purple. The BCP were determined in binary mixtures water with containing 0, 30, 40, 50, 60, and 70% (v/v) using spectrophotometric methods. results indicate dependence ratio ethanol. values log10Ka1 log10Ka2 correlated macroscopic (relative permittivity, ε) microscopic Kamlet–Taft parameters (α, β, π*) mixtur...

The solvation properties of ubiquinone-10 and ubiquinol-10 in a wide variety of solvents of polarity varying from alkanes to water are reported. Greatest solubility is observed in solvents of intermediate polarity and particularly where low polarity is combined with a pronounced tendency to interact with the benzoquinone substituent of the ubiquinone molecule. This includes solvents like chloro...

The value of systematic distribution between immiscible solvents for the resolution of mixtures has long been recognized, but it was not until the work of Craig (1) that its full potentialities were appreciated. With the development of an apparatus for carrying out a large number of simultaneous distributions between immiscible solvents, Craig and Post (2) introduced a new and very effective an...

Exposure monitoring by personal diffusive samplers, biological monitoring of toluene exposure by urinary hippuric acid determination, haematology, serum biochemistry for liver function, and a subjective symptom survey by questionnaire were conducted on 303 male solvent workers. They were exposed to a mixture of solvents including toluene (geometric mean 18 ppm), methyl ethyl ketone (MEK; 16 ppm...

A method of solvent sublation was developed for the enantioseparation of racemic ofloxacin (rac Oflx) and racemic tryptophan (rac Trp). In this method, dibenzoyl-L-tartaric acid (L-DBTA) and di-(2-ethylhexyl) phosphoric acid (D2EHPA) and sodium lauryl sulfate (SDS) were used as chiral coextractants and foamer, respectively. Several important parameters influencing the separation performances, s...

The conversion of chlorophyll a (Chl a) monomers into large aggregates in six polar solvents upon addition of water has been studied by means of absorption, fluorescence spectroscopy and fluorescence lifetime measurements for the purpose of elucidating the various environmental factors promoting Chl a self-assembly and determining the type of its organization. Two empirical solvent parameter sc...

Typical good nonpolar solvents for nonpolar polymers have values of the Flory interaction parameter of 0.3 or higher. This is striking since miscible nonpolar polymer blends exist with well-matched solubility parameters and resulting very small values of 10-2 or less. Using a cell model, it has been previously argued that there is a generic contribution to in polymer-solvent systems of about 0....