The self-assembled morphologies of amphiphilic ABC star triblock copolymers consisting of hydrophilic A blocks and hydrophobic B and C blocks and the blends with their counterpart linear AB diblock copolymers in solution are investigated by 2D real-space implementation of self-consistent field theory (SCFT) simulation. The star triblock copolymers self-assemble in solution to form various micel...

A series of polycarboxylate ether-based copolymers that include acrylic acid, 2acrylamido-2-methylpropane sulfonic acid, and polyethylene glycol-1000 was synthesized and the performance of these copolymers as rheology modifiers in aqueous alumina suspensions was characterized. We discussed the effect of monomer feed ratio and molecular weight on dispersing ability of these copolymers and on ext...

Copolymers of a liquid crystalline monomer, 2,5-bis[(4-methoxyphenyl)oxycarbonyl]styrene (MPCS), with St and MMA were prepared by free radical polymerization at low conversion in chlorobenzene with 2,20-azobisisobutyronitrile (AIBN) as initiator. The copolymers of poly(MPCS-co-St) and poly(MPCS-co-MMA) were characterized by H NMR and GPC. The monomer reactivity ratios were determined by using t...

Objective(s): Micelles have been studied as nanoparticulate drug delivery systems for improving the topical ocular delivery of hydrophobic drugs. The objective of this study was to develop and characterize dexamethasone-loaded polycaprolactone-polyethylene glycol-polycaprolactone (PCL-PEG-PCL) micelles to improve patient compliance and enhance the ocular bioavailability of poorly water-soluble ...

AIM Silicone oil is a useful tamponading material used in complex vitroretinal surgery. However, the use of silicone oil is associated with emulsification which can lead to vision threatening complications. The authors developed an experimental model to study the effect of encircling band on silicone oil emulsification. METHODS Two identical artificial eye chambers were constructed with circu...

Biotinylated and non-biotinylated copolymers of poly(ethylene oxide) (PEO) and poly(2-(diethylamino)ethyl methacrylate) (PDEAEMA) were synthesized by the atom transfer radical polymerization technique. The chemical compositions of the copolymers as determined by NMR are represented by PEO(113)PDEAEMA(70) and biotin-PEO(104)PDEAEMA(93), respectively. The aggregation behavior of these polymers in...

A Sporothrix variecibatus-inoculated biotrickling filter (BTF) was examined for styrene removal, without and with the addition of silicone oil, at different empty bed residence times. The highest elimination capacities (ECs) were 172.8 (without silicone oil) and 670 g m(-3)h(-1) (with silicone oil), respectively, corresponding to a 4-fold improvement in presence of oil. The addition of silicone...

In this work, new biodegradable ABCBA type pentablock copolymers with different mole ratio of L-lactide and PPDO-b-PEG-b-PPDO triblock copolymer were synthesized and characterized. In the first step, PPDO-b-PEG-b-PPDO triblock copolymer was synthesized via a ring-opening polymerization of P-DiOxanone (PDO) monomer with Poly (Ethylene Glycol) (P...

Microwave irradiation was used to synthesize PEG-PCL and PEG-PLA copolymers that are composed of biodegradable polymers including PEG, PLA, and PCL. These copolymers were used for loading docetaxel in nanoparticles. Single emulsion-solvent evaporation technique was applied for preparing the PEG-PLA and PEG-PCL mixed nanoparticles (micelles and polymersomes) with different proportions, including...