For the first time a top-down process was used to control the spatial location of Metal-Organic Frameworks on a surface. Deep X-ray lithography was utilised to micropattern a Zeolitic Imidazolate Framework layer on a sol-gel surface, with exposure hardening the sol-gel by inducing crosslinking while leaving the frameworks intact.

Titanium gels doped with water-soluble cationic porphyrin were synthesized by the sol–gel polymerization of Ti (OC4H9)4. In this work we investigate the spectroscopic properties along with SEM images of tetra carboxyl phenyl porphyrin when incorporated into porous matrix produced by the sol–gel technique. Keywords—TCPP; Titanium matrix; UV/Vis spectroscopy; SEM.

structural properties and chemical composition change the photocatalytic activity in tio2-sio2 nanopowder composite. the sio2-tio2 nanostructure is synthesized based on sol–gel method. the nanoparticles are characterized by x-ray fluorescents (xrf), x- ray diffraction (xrd), tunneling electron microscopy (tem), field emission scanning electron microscopy (fe-sem), uv-vis. spectrophotometer and ...

in order to improve uv and visible lights photocatalytic activities of the pure anatase tio2, a novel and efficient n-doped tio2 photocatalyst was prepared by sol-gel method. n-doped titania is prepared using triethylamine (with difference molar ratios) as the nitrogen source. the crystalline structure, morphology, particle size, absorbance and band-gap and chemical structure of n-doped tio2 wa...

the silica supported platinum nanoparticles was synthesized by using the sol-gel method. the possibility of using diamminedinitro platinum (ii) as pt precursor and effect of metal precursor concentration on the final pt nanoparticle size was investigated. a stable silica sol was prepared via hydrolysis of tetraethyl orthosilicate (teos) as a metal alcoxide and condensation reaction. subsequentl...

highly crystalline bi3+-doped cadmium oxide (cdo) sub-micron structures were synthesized by calcination the obtained precursor from a sol-gel reaction. the reaction was carried out with cadmium nitrate (cd(no3)2.4h2o), bismuth nitrate (bi(no3)3.5h2o) and ethylene glycol (c2h6o2) reactants without any additives at 80°c for 2h. resulting gel was calcined at 900 °c with increasing temperature rate...

the silica aerogel was prepared by the acid–base sol–gel polymerization of tetraethylorthosilicate precursor followed by ambient pressure drying. the prepared silica aerogels were characterized by fourier transform infrared )ft-ir(, thermo-gravimetric and differential thermal analysis )tg/dta(, x-ray diffractometer )xrd(, energy dispersive x-ray microanalysis )edx(, brunauer–emmitt–teller (bet)...

nano structured materials have wide range of applications due to their interesting size-dependent chemical and physical properties compared to particles of size in the range of micrometer. copper oxide nano materials are of interest on account of their potential uses in many technological fields. in this study  cuo nanoparticles were synthesized via simple sol gel method using basic cuso4 as we...

cobalt oxide (co3o4) nanorods were prepared by a simple co-precipitation method using ethanol solution of cobalt nitrate as precursor and cetyl trimethylammonium bromide (ctab) as surfactant. morphological properties of the nanoparticles were characterized. xrd measurement exhibited the structure of co3o4 nanocrystals for annealed samples. the sem images revealed that the particles changed from...

the aim of this study was to investigate the sol gel synthesis of ha/fa nanoparticles and the possible formation of tcp phase or unstoichiometric calcium deficient hydroxyapatite (cdha) from the precursors with a ca/p ratio of 1.62. in order to prepare the sol, the solutions of triethyl phosphite, ammonium fluoride and calcium nitrate in ethanol were used respectively as p, f and ca precursors....