The 4th positive and Cameron band emissions from electronically excited CO have been observed for the first time in 248-nm pulsed laser photolysis of a trace amount of CHBr(3) vapor in an excess of O atoms. O atoms were produced by dissociation of N(2)O (or O(2)) in a cw-microwave discharge cavity in 2.0 Torr of He at 298 K. The CO emission intensity in these bands showed a quadratic dependence...

We present a study of two-photon pathways for the transfer NaCs molecules to their rovibrational ground state. Starting from Feshbach molecules, we perform bound-bound excited state spectroscopy in wavelength range 900~nm 940~nm, covering more than 30 vibrational states $c \, ^3\Sigma^+$, $b ^3\Pi$, and $B ^1\Pi$ electronic states. Analyzing rotational substructure, identify highly mixed ^3\Sig...

Oscillator strengths of 23 electric-dipole-allowed bands of (14)N(2) in the 86.0-89.7 nm (111,480-116,280 cm(-1)) region are reported from synchrotron-based photoabsorption measurements at an instrumental resolution of 6.5x10(-4) nm (0.7 cm(-1)) full width at half maximum. The absorption spectrum comprises transitions to vibrational levels of the c(n) (1)Pi(u) (n=3,4), o(3) (1)Pi(u), and c(n+1)...

Single-walled nanotubes (SWNTs) produced by plasma laser vaporization (PLV) and containing oxidized surface functional groups have been studied for the first time with NEXAFS. Comparisons are made to SWNTs made by catalytic synthesis over Fe particles in high-pressure CO, called HiPco material. The results indicate that the acid purification and cutting of single-walled nanotubes with either HN...

We have fabricated bandpass filters based on pi-shifted long-period gratings for application in actively mode-locked erbium fiber lasers. Introducing the pi-phase shift in the middle of the grating opens a bandpass within the core-cladding mode resonance peaks. With a 22-nm bandwidth filter inserted in an actively mode-locked erbium fiber sigma laser, solitonlike pulses are generated, with a po...

It is well established that the superconductivity in the recently discovered superconducting compound MgB2 resides in the quasi-two-dimensional band (sigma band) and three-dimensional band (pi band). We demonstrate that, due to such band structure, the anisotropic Ginzburg-Landau theory practically does not have a region of applicability, because gradient expansion in the c direction breaks dow...

Suspension-feeding bivalves are considered efficient toxin vectors with a relative insensitivity to toxicants compared to other aquatic organisms. This fact highlights the potential role of detoxification enzymes, such as glutathione transferases (GSTs), in this bivalve resistance. Nevertheless, the GST system has not been extensively described in these organisms. In the present study, cytosolic...

For the two-body ${\bf B}_c\to{\bf B}M$ decays, where B}_c$ denotes anti-triplet charm baryon and B}(M)$ octet (meson), there exist two theoretical studies based on $SU(3)$ flavor [$SU(3)_f$] symmetry. One is irreducible $SU(3)_f$ approach (IRA). In representation, effective Hamiltonian related to initial final states forms amplitudes for B}M$. The other topological-diagram (TDA), $W$-boson emi...

A method for generating angular forces around sigma-bonded transition metal ions is generalized to treat pi-bonded configurations. The theoretical approach is based on an analysis of ligand-field and small-cluster Hamiltonians based on the moments of the electron state distribution. The functional forms that are obtained involve a modification of the usual expression of the binding energy as a ...

The heavier alkali-metal monosulfides (KS, RbS, CsS, and FrS) have been studied by high-level ab initio calculations. The RCCSD(T) method has been employed, combined with large flexible valence basis sets. All-electron basis sets are used for potassium and sulfur, with effective core potentials being used for the other metals, describing the core electrons. Potential-energy curves are calculate...