As alternative radiolytic approach, the synthesis of P3HT was made possible thanks to oxidation 3HT monomers by chloromethyl and dichloromethyl radicals or their corresponding peroxyl in situ produced dichloromethane solvent radiolysis. Under two different experimental conditions, oxygen-free solution oxygen-saturated solution, polymers, “P3HTN2” “P3HTO2” respectively, were successfully synthes...