using uv-vis spectrophotometic method, the formation constants for interaction of cd2+(aq) andco2+(aq) ions with l-alanine were experimentally studied at ph = 4.1 ± 0.01 (50mm of potassiumhydrogen phthalate buffer), ionic strength of 0.1m potassium nitrate and at 5 differenttemperatures 15,20, 25,30 and 35°c. the optical absorption spectra of mixtures containingconsidered cations and l-alanine ...

A synthetic approach for the preparation of a new class of highly conjugated unnatural α-amino acids bearing a 5-arylpyrazole side-chain has been developed. Horner-Wadsworth-Emmons reaction of an aspartic acid derived β-keto phosphonate ester with a range of aromatic aldehydes gave β-aryl α,β-unsaturated ketones. Treatment of these with phenyl hydrazine followed by oxidation allowed the regiose...

amino acids have been extensively used in several processes of the pharmaceutical and food industries. treatments for the recovery and reuse of the wastewaters generated from these processes are few and little known. this work aims at studying the influence of different variables on the sorption of l-cysteine, contained in aqueous solutions, on clinoptilolite mineral. l-cysteine (cys) was sorbe...

caviar is one of the valuable and most popular fish products all over the world that are obtained from sturgeons. nowadays, the wild resources of these fishes are diminished, therefore, to meet the demand for the product, farming sturgeons has been considered. the chemical composition and the amino acids profiles of the wild and farmed roe obtained from beluga (huso huso) were compared and the ...

an experiment was conducted to determine the dietary digestible lysine requirement of male and female broiler chickens (arian) during the period from 6 to 21 days post-hatching. an amino acid-fortified basal diet containing corn and soybean meal as intact protein sources provided 20 % cp, and 3200 kcal amen / kg. in this experiment 150 male and 150 female chicks were allocated on the basis of b...

We are presenting the synthesis of a phenylene ethynylene-based rod containing an Fmoc protected amino group and an activated acid which can be applied to peptide couplings. This linear amino acid analogue is applied to the synthesis of di-, tri- and pentamers. The pentamer has a molecular mass of 6.5 kDa and is characterized by (1)H NMR spectroscopy and MALDI-TOF MS. The method has potential f...

Title of Document: THE DEVELOPMENT OF NEW TOOLS FOR THE INVESTIGATION OF PROTEIN FUNCTION USING PHOTO-REACTIVE UNNATURAL AMINO ACIDS. Bryan Jason Wilkins, Doctor of Philosophy, 2010 Directed By: Dr. T. Ashton Cropp, Department of Chemistry and Biochemistry Reported here is the direct synthesis and application of unnatural amino acids for the development of exploratory tools for protein studies....

The first asymmetric synthesis of α-allyl-α-aryl α-amino acids by means of a three-component coupling of α-iminoesters, Grignard reagents, and cinnamyl acetate is reported. Notably, the enolate from the tandem process provides a much higher level of reactivity and selectivity than the same enolate generated via direct deprotonation, presumably due to differences in the solvation/aggregation sta...