We present a density-functional study of a binary phase-separating mixture of soft core particles immersed in a random matrix of quenched soft core particles of larger size. This is a model for a binary polymer mixture immersed in a cross-linked rigid polymer network. Using the replica "trick" for quenched-annealed mixtures we derive an explicit density functional theory that treats the quenche...

Mixed matrix membranes containing metal-organic frameworks have attracted large attention owing to the combined advantages of high separation performance and easy processability. In this work, CO2-philic zirconium metal organic framework UiO-66 and UiO-66-NH2 nanocrystals were synthesized and embedded into polyether block amide (PEBA) polymer membranes for CO2 separation. It can be found that a...

The special topic ‘‘Metaland Polymer-Matrix Composites’’ is intended to capture the state of the art in the research and practice of functional composites. The current set of articles related to metal-matrix composites includes reviews on functionalities such as self-healing, self-lubricating, and selfcleaning capabilities; research results on a variety of aluminum-matrix composites; and invest...

A symmetrized Density Matrix Renormalization Group procedure together with the correction vector approach is shown to be highly accurate for obtaining dynamic linear and third order polarizabilities of one-dimensional Hubbard and U−V models. The U−V model is seen to show characteristically different third harmonic generation response in the CDW and SDW phases. This can be rationalized from the ...

This paper reports the results of intermatrix synthesis (IMS) of silver metal nanoparticles (Ag-MNPs) in Purolite C100E sulfonic ion exchange polymer of the gel-type structure. It has been shown that the surface morphology of the initial MNP-free polymer is absolutely smooth, but it dramatically changes after the kinetic loading of Ag on the polymer and then IMS of Ag-MNPs. These morphological ...

   To fabricate a defect free and high performance mixed matrix membrane (MMM), one approach is the functionalization of inorganic nanofillers (as dispersed phase) in the organic polymer matrix (as continuous phase) to modify the interactions between two phases.  For this purpose,, raw multi-walled carbon nanotubes (rMWCNTs) were purified by acid mixture (HNO3/H2SO<sub...

Small polymeric nanoparticles sized below 10 nm were effectively synthesized via free radical polymerization of a cross-linker in a glassy polymer matrix, owing to the successful prohibition of aggregation between the primary nanoparticles by the matrix.

(2014) Surface functionalization on the thermal conductivity of graphene–polymer nanocomposites. which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The moral rights of the named author(s) have been asserted. Notice: Changes introduced as a result of publishing processes such as copy-editing and formatting may not be reflec...

We propose a polymer photovoltaic device with a new scattering mechanism based on photon absorption and re-emission in a quantum dot layer. A matrix of aluminum nanorods with optimized radius and period are used to modify the coupling of light emitted from the quantum dots into the polymer layer. Our analysis shows that this architecture is capable of increasing the absorption of an ordinary po...

In a metal-free procedure, chelating thiol groups and an electrophile react to assemble a robust, conjugated porous polymer with pendant aldehyde functionalities. These groups are able to reduce Ag(i) ions to generate, in situ, Ag(0) nanoparticles evenly dispersed in the polymer matrix. The Ag(0)-polymer composite enables selective reduction of aromatic nitro compounds as a heterogeneous cataly...