نتایج جستجو برای: polarography
تعداد نتایج: 769 فیلتر نتایج به سال:
Voltammetric measurements of dissolved surface-active substances in aqueous solutions, as specific commercial detergents, are described in the present paper. Two voltammetric methods based on the adsorption phenomena at mercury electrode/aqueous solution interface were performed in order to obtain the analytical signal for the detergent analysis. The first method was direct current polarography...
We describe four patients from three independent families with the m.1644G>A in the MT-TV gene, previously reported without demonstration of its deleterious impact. Very high mutation proportion co-segregated with cytochrome oxidase defect in single muscle fibers and respiratory defect in cybrids as shown by spectrophotometric assays and polarography. The mutation appeared to have a very steep ...
چکیده ندارد.
The reaction of nitrite ion with ascorbic acid and its effect on the rate of nitrosation of secondary amines have been investigated by differential pulse polarography in aqueous acidic solution. Ascorbic acid shows nonuniform behavior: it accelerates the nitrosation of N-methylaniline between pH 1.00 and 1.95, allows the nitrosation of diphenylamine and iminodiacetonitrile, but inhibits the nit...
A differential-pulse polarographic (DPP) method was developed for the determination of brodimoprim (BDP) in Michaelis (MCL) buffer. The peak potential (Ep) occurs at 21.33 V (versus SCE) when the pH of the system is 4.0. The voltammetric behaviour in MCL buffer and the mechanisms of the electrode reaction were studied by, e.g., linear sweep voltammetry, cyclic voltammetry and normal-pulse polar...
Sublethal exposures of the marine amphipod Gammarus locusta to a concentration range of copper (Cu) in water (4 days' exposure; 3, 5 and 10 micro g Cu l(-1)) or spiked sediments (28 days' exposure; 1, 3 and 6 mg Cu kg(-1) dry weight) were performed, and the resulting bioaccumulation of Cu and effects on putative metallothionein (MT) and lipid peroxidation (LP) were investigated. A time-course e...
A novel electroanalytical procedure is proposed for the determination of the triflumizole in formulation, soil and natural water samples using differential pulse polarography (DPP). Triflumizole exhibited a single well-defined cathodic peak over the pH range of 1.0-9.0 in Britton-Robinson (B-R) buffers. The peak potentials were shifted to more negative values upon increasing the pH and a plot o...
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