Degradation of metal-organic halide perovskites when exposed to ambient conditions is a crucial issue that needs to be addressed for commercial viability of perovskite solar cells (PSCs). Here, a concept of encapsulating CH3NH3PbI3 perovskite crystals with a multi-functional graphene-polyaniline (PANI) composite coating to protect the perovskite against degradation from moisture, oxygen and UV ...

Perovskite solar cells fabricated from organometal halide light harvesters have captured significant attention due to their tremendously low device costs as well as unprecedented rapid progress on power conversion efficiency (PCE). A certified PCE of 20.1% was achieved in late 2014 following the first study of long-term stable all-solid-state perovskite solar cell with a PCE of 9.7% in 2012, sh...

Ab initio molecular dynamic (AIMD) simulations were performed to calculate the equation of state (EOS) of CaSiO3 perovskite at mantle pressure–temperature conditions. At temperatures above 2000 K, even though the hydrostatic crystal structure is metrically tetragonal in the pressure range of 13–123 GPa, the symmetry of the elastic moduli is consistent with cubic symmetry. Our results show that ...

Thermochemical water and carbon dioxide splitting with concentrated solar energy is a technology for converting renewable solar energy into liquid hydrocarbon fuels as an alternative to fossil fuels, which are dominating in today's energy mix. For the conversion reaction to be efficient, special redox materials are necessary to perform the necessary chemical reactions in a thermochemical cycle....

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim wileyonlinelibrary.com 1606525 (1 of 10) Conventionally, optoelectronic devices adopt planar perovskite configurations. Compared with planar thin films, nanostructured semiconductors offer unique optical properties. In photovoltaics, semiconductor gratings integrated with metal electrodes have been utilized to excite surface plasmons[6] and incr...

Rapid progress in the synthesis of nanostructures with tailor-made morphologies necessitates adequate analytical tools to unravel their physical properties. In our study, we investigate, on the nanometer scale, the band gap of individual [TBAxH1−x] [Ca2Nb3O10] − nanosheets obtained through intercalation−exfoliation of the layered bulk phase KCa2Nb3O10 with tetra-n-butylammonium hydroxide (TBAOH...

The area of thin-film photovoltaics has been overwhelmed by organometal halide perovskites. Unfortunately, serious stability concerns arise with perovskite solar cells. For example, methyl-ammonium lead iodide is known to decompose in the presence of water and, more severely, even under inert conditions at elevated temperatures. Here, we demonstrate inverted perovskite solar cells, in which the...

Perovskite films are a promising candidate for future highly efficient and low-cost solar cells. The long diffusion length of charge carriers in the perovskite film makes its architecture fabrication seem unnecessary, while the rapid crystallization process increases the difficulty in its architecture fabrication. Here we show the fabrication of perovskite architectures through a nucleation med...

An optimal small amount of water added into methyl ammonium iodide (MAI) solution in isopropyl alcohol (IPA) helps perovskite crystallization and leads to larger grain size from sequential deposition of perovskite films. The concentration of water was varied from 1% to 7% (vol% of IPA) in MAI solution and optical absorption, crystallization, morphology of perovskite films and their photovoltaic...

In recent years perovskite based solar cells have become a promising photovoltaic technology, most notable for their high power conversion efficiencies and potential for cheap solution-processable module production. This report identifies the ongoing research and development into the behaviour of the perovskite material as a semiconducting active area and the ever improving fabrication of perov...