A 'co-templating' strategy supported by molecular modelling has been used to prepare, for the first time, silicoaluminophosphates with the SAV and KFI framework topologies, each of which has a three-dimensionally connected pore system with high specific volume.

Very small ( approximately 2 nm) silver nanoparticles can be readily prepared using p-phosphonated calixarenes as templating agents and surfactants, at the same time allowing the use of hydrogen gas as an environmentally benign reductant.

Electrochemical fabrication integrating templating strategies have paved the way for creating mesoporous metal alloy films with distinctive pores and functionalities electrocatalysis, fuel cells, sensor (bio) development.

Abasic sites represent the most frequent DNA lesions in the genome that have high mutagenic potential and lead to mutations commonly found in human cancers. Although these lesions are devoid of the genetic information, adenine is most efficiently inserted when abasic sites are bypassed by DNA polymerases, a phenomenon termed A-rule. In this study, we present X-ray structures of a DNA polymerase...

A major base lesion resulting from oxidative stress is 8-oxo-7,8-dihydro-2'-deoxyguanosine (8-oxoG) that has ambiguous coding potential. Error-free DNA synthesis involves 8-oxoG adopting an anti-conformation to base pair with cytosine whereas mutagenic bypass involves 8-oxoG adopting a syn-conformation to base pair with adenine. Left unrepaired the syn-8-oxoG/dAMP base pair results in a G-C to ...

AIM The accuracy and inter-observer reliability (IOR) of acetate templating on hard copy X-rays in 33 primary total hip arthroplasties as measured by consultant and trainee surgeons was analyzed to find out how accurate are junior surgeons undertaking specialty training. METHODS The study was questionnaire-based using a prospective cohort over a 4 weeks period. The Surgeon measurements of ace...

A high performance Na-ion capacitor has been assembled by using S-doped carbon sponges and highly porous produced from biomass-derived products sustainable salt-templating approaches.

A computationally assisted approach has enabled the first catemeric polymorph of carbamazepine (form V) to be selectively formed by templating the growth of carbamazepine from the vapour phase onto the surface of a crystal of dihydrocarbamazepine form II.

Using a one-pot approach employing true liquid crystal templating on neutral surfactants and simple metal salt precursors, mesostructured, mesoporous silicates have been prepared in which bimetallic nanoparticles are deposited; magnetic properties of PtCo systems so prepared are evaluated.

Deep eutectic solvents (DESs) represent an emergent class of green designer that find numerous applications in different aspects chemical synthesis. A particularly appealing aspect DES systems is their simplicity preparation, combined with inexpensive, readily available starting materials to yield properties (negligible volatility, non-flammability and high solvation capacity). In the context p...