The interface between the tetrathiafulvalene/tetracyanoquinodimethane (TTF-TCNQ) organic blend and the Au(111) metal surface is analyzed by Density Functional Theory calculations, including the effect of the charging energies on the molecule transport gaps. Given the strong donor and acceptor characters of the TTF and TCNQ molecules, respectively, there is a strong intermolecular interaction, w...

Printing fully solution-processed organic electronic devices may potentially revolutionize production of flexible electronics for various applications. However, difficulties in forming thin, flat, uniform films through printing techniques have been responsible for poor device performance and low yields. Here, we report on fully solution-processed organic thin-film transistor (TFT) arrays with g...

Chemical composition and physico-chemical characteristics of natural and ex-situ reconstructed sea surface microlayer samples were studied using a complex methodological approach. Surface microlayer samples and the underlying seawater were collected in different seasons and different weather conditions in the northern most part of the Adriatic sea. The techniques used were thin layer chromatogr...

An organic photovoltaic cell was fabricated, with the configuration ITO/zinc phthalocyanine (ZnPc)/N,N0-diheptyl-3,4,9,10perylenebiscarboximide (PTCDI-C7) (PTCDI)/Ga:In. PTCDI is a liquid crystal and acts as an electron acceptor organic material while ZnPc corresponds to a donor. The cell performance under illumination was examined with different organic layer thickness. A cell incorporating 25...

In situ synchrotron x-ray diffraction studies of the nucleation of barium fluoride from supersaturated solutions, at fatty-acid monolayer templates, reveal a commensurate relationship between the interfacial lattices of the organic molecules and the inorganic atoms. At the onset of growth, the barium fluoride layer is very thin and the lateral unit cell is contracted by as much as 4%; at the sa...

Recent advances in inkjet-printed organic field-effect transistors (OFETs) based on organic semiconductor/insulating polymer blends are reviewed in this article. Organic semiconductor/insulating polymer blends are attractive ink candidates for enhancing the jetting properties, inducing uniform film morphologies, and/or controlling crystallization behaviors of organic semiconductors. Representat...

The organic solvent extraction of Armillaria mellea showed different highly intrinsic fluorescent compounds either in rhizomorph or in hyphae (F , F , F , MF , MF and MF ). The characterization of ultraviolet and fluoro-spectrophotometry of these compounds has been exhibited. Thin layer chromatography and fluorescent spectrum of hyphae and rhizomorph indicated an additional compound (FH) ...

We have succeeded in developing high-performance ptype of organic semiconductors with phenylethynyl groups, which have high filed-effect mobilities (> 3 cm2V−1s−1) by improving molecular planarity. A single crystal of the organic semiconductors has a herringbone structure. It plays an important role for carrier transport. In addition, we found that they had lower contact resistances to Au elect...

TiO(2)-based photocatalysis has been widely used to decompose various organic pollutants for the purpose of environmental protection. Such a "green" photochemical process can ultimately degrade organic compounds into CO(2) and H(2)O under ambient conditions. We demonstrate here its extended application on the engineering of single- or few-layer graphene. Using a patterned TiO(2) photomask, we h...

From distribution measurements using dilute solutions both the extraction equilibrium constant and the dissociation constant for the ion pair are obtained. The free energy of transfer of the two ions are also obtained from the same experiment. From these constants and distribution measurements in solutions, more concentrated than those above, the degree of dissociation in the organic layer is o...