نتایج جستجو برای: optical rotation
تعداد نتایج: 333642 فیلتر نتایج به سال:
The large scale magnetic fields of our Galaxy have been mostly revealed by rotation measures (RM s) of pulsars and extragalactic radio sources. In the disk of our Galaxy, the average field strength over a few kpc scale is about 1.8 µG, while the total field, including the random fields on smaller scales, has a strength of about 5 µG. The local regular field, if it is part of the large scale fie...
The properties of periodic pairs of mutually twisted metallic (silver) crosses separated by dielectric layer have been investigated by numerical simulation. The results show that the exceptionally strong polarization rotation and circular dichroism, negative permeability and negative refractive index are found at the infrared communication wavelength (1.55 microm).
Optical activity in the X-ray range stems from the electric-dipole-electric-quadrupole interference terms mixing multipoles of opposite parity, and can be observed exclusively in systems with broken inversion symmetry. The gyration tensor formalism is used to describe the X-ray optical activity in langasite La3Ga5SiO14 crystal with the P321 space group. An experimental study of the X-ray natura...
The successful launch of ENVISAT in March 2002 has given a great opportunity to understand the changes of water colour with high spatial resolution. In this study, the potential of MERIS sensor to describe variations of optically active substances of Alqueva artificial lake is investigated. Regular in situ measurements, from May 2004 to July 2005, are used in combination with MERIS acquisitions...
A series of novel naphthalene attached bis-oxazines were synthesized and characterized. The bis-oxazines were studied by VT-NMR analysis to assess the possibility of conformational twist. The bis-oxazine prepared from (l)-methylvalinate show a helical conformational twist in the single crystal X-ray analysis. Three isomers of bis-oxazines were prepared from chiral α-methylbenzyl amines, the mes...
The magneto-optical activity, namely the polarization conversion capabilities of high-index, non-absorbing, core-shell dielectric nanospheres is theoretically analyzed. We show that, in analogy with their plasmonic counterparts, the polarization conversion in resonant dielectric particles is linked to the amount of electromagnetic field probing the magneto-optical material in the system. Howeve...
Using the unique features of the electronic band structure of GaN(x)As(1-x) alloys, we have designed, fabricated and tested a multiband photovoltaic device. The device demonstrates an optical activity of three energy bands that absorb, and convert into electrical current, the crucial part of the solar spectrum. The performance of the device and measurements of electroluminescence, quantum effic...
Chiral media are characterized by preferential interaction with either left- or right- circularly polarized radiation, whereupon an optically active medium and its enantiomorph possess rotary powers of opposing sign due to mirror handedness of their micro- or nano-structures. Here, we report on the first time-resolved investigations of few-cycle pulse propagation along the axis of a sub-wavelen...
A new proline-based aminophenol ligand was synthesized by a convenient procedure. The ligand was characterized by (1)H NMR, (13)C NMR and IR spectroscopies, elemental analysis and optical activity measurements. Mononuclear iron(III) complex (FeL(Pro)) of this ligand was synthesized and characterized by IR, UV-vis, ESI-MS, magnetic susceptibility studies and cyclic voltammetry techniques. The eq...
The aggregates of a cationic polythiophene (PT1) formed in poor solvent in the presence of sugars showed the distinct circular dichroism activity, the intensity being well correlated with the specific optical rotation [α] of sugars: therefore, the present system is useful as a novel sugar structure reading-out method.
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