The analysis of geometric phases associated with level crossing is reduced to the familiar diagonalization of the Hamiltonian in the second quantized formulation. A hidden local gauge symmetry, which is associated with the arbitrariness of the phase choice of a complete orthonormal basis set, becomes explicit in this formulation (in particular, in the adiabatic approximation) and specifies phys...

We present a new simulation model of the reactions in the photosynthetic electron transport chain of C3 species. We show that including recent insights about the regulation of the thylakoid proton motive force, ATP/NADPH balancing mechanisms (cyclic and noncyclic alternative electron transport), and regulation of Rubisco activity leads to emergent behaviors that may affect the operation and reg...

The isomorphism problem for finitely generated Coxeter groups is the problem of deciding if two finite Coxeter matrices define isomorphic Coxeter groups. Coxeter [3] solved this problem for finite irreducible Coxeter groups. Recently there has been considerable interest and activity on the isomorphism problem for arbitrary finitely generated Coxeter groups. In this paper, we determine some stro...

We investigated the dynamics of excited-state proton transfer (ESPT) of photo-amphiprotic 7-hydroxyquinoline (7HQ) in the presence of a hydrogen (H)-bond bridging diol in a polar aprotic medium. The formation of 1 : 1 H-bonded complexes of 7HQ with various diols of different alkane chain lengths was revealed using steady-state electronic spectroscopy. With femtosecond-resolved fluorescence spec...

1. Exposure of chloroplasts to sonic oscillation in a medium of low osmolarity rapidly inactivated the Hill reaction, photophosphorylation, and photooxidation of ascorbate in the presence of dichlorophenyl-1 , 1 -dimethylurea. Concurrently with this inactivation plastocyanin was liberated from the chloroplasts. The addition of plastocyanin during sonic oscillation prevented net loss of plastocy...

Lithium cation solvation structures [Li(S)(n=1-4)](+) with ligands of cyclic or noncyclic carbamate-modified disiloxanes are optimized at B3LYP level of theory and compared to their corresponding simplified carbamates and to the organic carbonates ethylene carbonate (EC) and dimethyl carbonate (DMC). The electrostatic potentials (ESP) of these investigated carbonyl-containing solvents are mappe...