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Ru3(μ-CO)3(CO)5-type clusters bound to the dinucleating PNNP expanded pincer ligand are described. Deprotonation of a methylene linker gives an anionic triruthenium cluster featuring dearomatized ligand. Interestingly, H2 activation by resulting appears not proceed through metal-ligand cooperativity.
OBJECTIVES The aim of our study was to assess the impact of plasma HIV-1 RNA level [viral load (VL)] variation and tenofovir exposure on kidney functions by analysing changes in calculated glomerular filtration rates (GFRs) over a 48 week period in patients with mild renal impairment. PATIENTS AND METHODS A prospective observational study that included data from all consecutive HIV-infected p...
Abstract In this work, the impact of different Cu(In 1‐x Ga x )(Se 1‐y S y ) 2 solar cell structures on shift dominant recombination region at varying light intensities was investigated. A new parameter proposed to account for relative minimum band gap location in a graded absorber. Additionally, influence shunt resistances CIGSSe modeled. Within investigated illumination range, correlations be...
In the present work, the effect of Ca(NO3)2.4H2O and (NH4)2HPO4 primary solutions as the beginning materials in synthesis of a calcium phosphate phase, was examined. So, we investigated the wet chemical reactions in solution at different temperatures by a hydrothermal condition aimed at hydroxyapatite (Ca10(PO<su...
Heterogeneous reaction of NO2 with CaCO3, an abundant and reactive component in mineral dust aerosol, was investigated this work at different relative humidifies (RH, up to 80%), using a fixed-bed reactor. Ion chromatograph vapor sorption analyzer were employed measure changes particulate nitrate water time (up 24 h). When concentration ∼10 ppmv (∼2.5 × 1014 molecule cm−3), CaCO3 showed very lo...
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