Employing the strategy of quaternization of the 2,2' N atoms of the conjugated bipyridine ligand 1,4-bis[2-(4'-methyl-2,2'-bipyrid-4-yl)ethenyl]benzene (L), a polypyridyl complex of ruthenium(II) was tethered on the surface of zeolite Y. Electrochemical and spectroscopic properties of the complex suggest that, upon visible photoexcitation of the MLCT band, the electron is localized on the conju...

Top-down approach has been viewed as an efficient and straightforward method to prepare nanosized zeolites. Yet, the mechanical breaking of zeolite causes amorphization, which usually requires a post-milling recrystallization to obtain fully crystalline nanoparticles. Herein we present a facile methodology to prepare zeolite nanocrystals, where milling and recrystallization can be performed in ...

A characterization of Ti-Beta zeolites synthesized under various conditions as well as an investigation of their photocatalytic properties for the reduction of CO2 with H2O at 323 K to produce CH4 and CH3OH were carried out. In situ XAFS spectra measurements indicated that a highly dispersed tetrahedral titanium oxide species was present in the zeolite framework and an increase in the coordinat...

The purpose of this study was to evaluate various biological effects of silver-zeolite and a polyphenol-rich extract of A. nodosum (ASCOP) to prevent and/or treat biofilm-related oral diseases. Porphyromonas gingivalis and Streptococcus gordonii contribute to the biofilm formation associated with chronic periodontitis. In this study, we evaluated in vitro antibacterial and anti-biofilm effects ...

Lubricant oils take significant part in current health and environmental considerations since they are an integral and indispensable component of modern technology. Antioxidants are probably the most important additives used in oils because oxidative deterioration plays a major role in oil degradation. Zeolite nanoparticles (NPs) have been proven as another option as green antioxidants in oil f...

The unique properties of microporous zeolites, including ion-exchange properties, adsorption, molecular sieving, catalysis, conductivity have been exploited in improving the performance of gas sensors. Zeolites have been employed as physical and chemical filters to improve the sensitivity and selectivity of gas sensors. In addition, direct interaction of gas molecules with the extraframework ca...

polycrystalline mfi zeolite membranes were prepared on α-alumina tubular support by hydrothermal treatments at 413 k. the synthesized zeolite membranes were characterized by xrd, sem and single gas permeation. the influence of hydrothermal treatment steps and the calcination time on the zeolite layer formation were investigated. mfi zeolite membrane prepared by four subsequent hydrothermal trea...

background: there are great resources of natural zeolite in iran. zeolite, an inorganic ion-exchanger, may be used as a suitable technical-economical solution for water treatment in many regions of iran. in this study, the characterization of natural zeolite natrolite and the feasibility of removing hardness, cations, and anions were investigated. methods: first, zeolite composition and type we...

Khorvash, M., Colombatto, D., Beauchemin, K. A., Ghorbani, G. R. and Samei, A. 2006. Use of absorbants and inoculants to enhance the quality of corn silage. Can. J. Anim. Sci. 86: 97–107. This study examined whether inoculants and various absorbent materials could be used during ensiling to reduce effluent losses and improve nutritive value of corn silage. Two corn forages were harvested: conve...