An efficient synthetic method for successful synthesis of amine denderon on SBA-15 and related Pd (II) complex has been developed. This modified mesoporous material was characterized by various techniques such as TEM, XRD, atomic absorption spectroscopy, N2 adsorption-desorption, and FT-IR. The catalytic activities of the prepared catalysts were investigated by employing aerobic oxidation of al...

This study focused on the leaching process for the recycling of Li, Ni, Co, and Mn from the LiNixCoyMnzO2 (NCM) cathodes of spent lithium-ion batteries (LIBs). Eh–pH diagrams were used to analyze suitable leaching conditions. Operating variables, such as the concentration of H2SO4 (0.5–2.5 M), concentration of H2O2 (0–1 vol%), temperature (10–50 °C), stirring speed (400–800 rpm), and solid/liqu...

The retention of nutrients in narrow, vegetated riparian buffer strips (VBS) is uncertain and underlying processes are poorly understood. Evidence suggests that buffer soils are poor at retaining dissolved nutrients, especially phosphorus (P), necessitating management actions if P retention is not to be compromised. We sampled 19 buffer strips and adjacent arable field soils. Differences in nut...

Increasing nitrate levels in groundwater have been attributed to inappropriate nitrogen (N) management. The application rates, timing, and methods of both N fertilization and irrigation are important management tools that determine and control the fate and behavior of N in soilÿplant systems. For example, multiple applications with small amounts of fertilizer (e.g. split application) usually en...

The aim of this work is to model the occurrence and intensity of calcium carbonate loss in calcareous forest soils under Mediterranean conditions. We have used 193 Spanish forest soils found on limestone parent material considered highly calcareous materials. This data set came from FOREDAF, a database containing 2200 complete soil profiles and all of them covered by forest stands (mainly domin...

Monolithic waste materials (e.g. Portland cement treated wastes) in many field scenarios do not remain continuously saturated, but experience intermittent wetting interspersed with periods of storage in an unsaturated environment. During storage, the matrix may loss moisture to the environment, promoting precipitation or redistribution of species. In addition, the matrix may react with the surr...

Advances in Agronomy, Volume 86 Copyright 2005, Elsevier Inc. All rights reserved. 0065-2113/05 $35.00 II. C limatic and Soil Conditions of Study Areas III. N utrient Stocks IV. N utrient Cycling A. N utrient Removal: Yield B. N utrient Removal: Leaching C. N utrient Removal: Soil Erosion D. A ddition of Nutrients E. T ransfer of Nutrients V. N utrient Balances VI. S oil Changes Under Cocoa VII...

The N available after legumes is sufficient for maximum crop yields in many cropping systems. Fertilizing without accounting for the "extra" N mineralized from legume residues can contribute to high nitrate-N concentrations in the soil during crop production and increase nitrate-N leaching potential. Tillage practices also affect the physical, biological, and chemical nature of the soil, changi...

outcomes to readily measurable parameters, we should be able to better optimize management within different We tested the hypothesis that particulate organic matter (POM) regions and cropping systems. and aggregate dry mean weight diameter (DMWD) are related to This work follows up on previous findings suggesting fertilizer-use efficiency (FUE) and leaching susceptibility. Soil cores measures o...

Adoption of new management techniques that improve soil water storage and soil N plant availability yet limit N leaching may help improve environmental quality. A benchtop study was conducted to determine the influence of a single urea fertilizer rate (224 kg N ha) applied with band or fully mixed zeolite (clinoptilolite) application rates (up to 90 Mg ha) on NH4-N and NO3-N concentrations in a...