Metallic molybdenum (Mo(o)) wires with diameters ranging from 15 nanometers to 1.0 micrometers and lengths of up to 500 micrometers (0.5 millimeters) were prepared in a two-step procedure. Molybdenum oxide wires were electrodeposited selectively at step edges and then reduced in hydrogen gas at 500 degrees C to yield Mo(o). The hemicylindrical wires prepared by this technique were self-uniform,...

A molybdenum L-edge X-ray absorption spectroscopy (XAS) study is presented for native and oxidized MoFe protein of nitrogenase as well as Mo-Fe model compounds. Recently collected data on MoFe protein (in oxidized and reduced forms) is compared to previously published Mo XAS data on the isolated FeMo cofactor in NMF solution and put in context of the recent Mo K-edge XAS study, which showed a M...

The reagent 4-hydroxybenzaldehyde thiosemicarbazone (4-HBTS) has been used for the determination of Mo(VI) by spectrophotometric method. The reagent 4-HBTS gives green colour with Mo(VI) solution of weak acidic medium and the maximum absorbance was observed at 365nm, in acidic buffer p H 6.0. The molar absorptivity and Sandell’s sensitivity of Mo(VI)4-HBTS complex are 1.25 x 10 L mol cm and 0.0...

Molybdenum disulfide is one of the best known solid lubricants, and although it originally gained popularity in aerospace and military applications, it is now commonly found in a variety of lubrication applications. It is widely used in greases and specialized grease-like products known as pastes, in fluid lubricants such as automotive and industrial gear oils, in solid film lubricants includin...

The isolation of the two-dimensional semiconductor molybdenum disulphide introduced a new optically active material possessing a band gap that can be facilely tuned via elastic strain. As an atomically thin membrane with exceptional strength, monolayer molybdenum disulphide subjected to biaxial strain can embed wide band gap variations overlapping the visible light spectrum, with calculations s...

A 70-year-old man with an uncemented metal-on-polyethylene total hip prosthesis underwent revision arthroplasty 33 months later because of pain, swelling and recurrent dislocation. There appeared to be corrosion and metal release from the prosthetic head, resulting in pseudotumour formation and severe local soft-tissue destruction. The corrosion occurred at the junction between the titanium-mol...

During the screening for Rhodobacter capsulatus mutants defective in xanthine degradation, one Tn5 mutant which was able to grow with xanthine as a sole nitrogen source only in the presence of high molybdate concentrations (1 mM), a phenotype resembling Escherichia coli mogA mutants, was identified. Unexpectedly, the corresponding Tn5 insertion was located within the moeA gene. Partial DNA sequ...

Introduction EPR was the first spectroscopic method other than UV/visible spectroscopy to be applied systematically to investigations of the structure and functioning of metalloenzymes. The first such EPR studies of xanthine oxidase were reported in 1959 [l]. Since one reduced state of each of the four redox-active centres in the molecule is EPRactive, there is obviously considerable potential ...

Lattice strains were measured as a function of the angle c between the diffracting plane normal and the stress axis of a diamond anvil cell in a layered sample of molybdenum and gold. The sample was compressed over the range 5–24 GPa and the lattice strains were measured using energy-dispersive x-ray diffraction. As c is varied from 0° to 90°, the mean lattice parameter of molybdenum increases ...

Advanced high strength steels (AHSS) are used for car body applications in the automotive industry to improve passenger safety, improve fuel efficiency and to lower harmful carbon emissions. Galvannealed AHSS are used to provide corrosion protection. AHSS are alloyed with several elements such as Mn, Si, Al, P, Mo, etc. to achieve better mechanical properties. However, the knowledge of the effe...