Nonequilibrium states of matter are arousing huge interest because of the outstanding possibilities to generate unprecedented structures with novel properties. Self-organizing soft matter is the ideal object of study as it unifies periodic order and high dynamics. Compared to settled systems, it becomes vital to realize more complex interaction patterns. A promising and intricate approach is im...

Physico-chemical studies of some aqueous surfactant solutions were carried out by employing conductance, surface tension and spectrofluorometric techniques. From conductivity and surface tension measurements, critical micelle concentration (CMC), counter-ion association (α), equivalent conductance at infinite dilution (٨0), surface excess concentration (Γ), minimum area per molecule (Amin), sur...

We perform Monte-Carlo simulations of a binary, strongly separated mixture of A- and B-type homopolymers with some amount of random AB copolymers added. The interface is analyzed and the interface tension is calculated using the model of capillary waves. We can clearly demonstrate that random copolymers are localized at real, fluctuating interfaces between incompatible polymer species and micel...

Pluronic/bile salt/phospholipid mixed micelles (Pluronic/BS/PS-MM) drug carrier system for solubilization hydrophobic drugs was developed. A typical hydrophobic compound, pyrene, was selected as a representative hydrophobic compound to model the hydrophobic drugs. Five Pluronics, F68, F88, F98, F108, and F127 with different PPO chain length were studied. CMC data and solubilization capacities w...

The mutual interaction between 5, 5-diphenyl hydantoin sodium salt (C15H11N2NaO2) also known as dilantin sodium (DS) and surfactants like sodium dodecyl sulphate (SDS) and cetyltrimethylammonium bromide (CTAB) has been studied by measuring the variation of their aggregation properties in pressence of each other. Critical micelle concentration (CMC) of DS determined by spectrophotometric and con...

Efficient formulations used in hydrometallurgy are often based on synergistic action of two oil-soluble extractants at an optimized mole fraction. In this series papers, we describe the N,N’-dimethyl-N,N’-dioctylhexylethoxymalonamide (DMDOHEMA)/di(2-ethylexyl) phosphoric acid (HDEHP) system, and how expression effect varies with acidity, using three common representations: distribution ratios, ...

Aggregation behaviour of cefprozil monohydrate (C18H19N3O5S.H2O), an antibiotic, has been studied in presence of sodium dodecyl sulphate (SDS) and Cetyltrimethylammonium bromide (CTAB). Critical micelle concentration (CMC) of drug is determined to be 0.34 mM and is observed to decrease significantly at SDS < 2 mM. Above this concentration increase is less prominent and remains almost constant. ...

The observation of a micellar cubic phase is reported for a mixture of an antimicrobial peptide from the Lactoferrin family, LFampin 265-284, and a model membrane system of dimyristoylphosphatidylcholine/dimyristoylphosphatidylglycerol (3:1), as derived from small-angle x-ray diffraction (SAXD) measurements. The system shows remarkable thermotropic polymorphism: the peptide disrupts the lipid b...

We present a numerical study on the phase diagram for a simple model of Janus colloids, including ordered and disordered structures. Using a range of techniques, we generate a set of crystal structures and investigate their relative stability field in the pressure-temperature and temperature-density planes by means of free-energy calculations and thermodynamic integration schemes. We find that ...

Microcalorimetric and spectropolarimetric titrations were used to investigate micellization of cationic surfactants and binding of netropsin to dodecameric DNA duplex. For description of both processes, model functions containing linear and non-linear parameters were derived. Model analysis was based on a weighted (multi)linear regression and a standard »Simplex« procedure. Close investigation ...