Electrode potential measurements have been applied to study electrical characteristics like transport numbers, permselectivity & fixed charge density of ion-exchange membranes. Membrane potential measurements were made across zirconium phosphotungstate cation-exchange membrane maintained at 27◦C, using halide salts of alkali & alkaline earth metals as electrolytes. The effect of concentration o...

in this work we introduce a practical use of synthesized schiff base metal complex in sensing application. a new perchlorate-selective electrode based on the complex n, n'-4-nitro-phenylmethanebis-(salicylaldiminato) copper (ii) [cul] as the membrane carrier was developed. the electrode exhibits a good  nernstian slope of -55.0 ± 1.0 mv/decade and a linear range of  for perchlorate. the limit o...

Voltammetric ion-selective electrodes (ISEs) based on poly(3-octylthiophene) (POT) in connection with ultra-thin membranes formulated different selective receptors (i.e., ionophores) are proposed for detection of lead, copper and silver ions (Pb2+, Cu2+ Ag+). The working mechanism the POT-membrane electrode is interconnected charge transfer processes both sides membrane, overall process dependi...

A nanocomposite membrane Cu2+ ion-selective electrode has been constructed using a new compound ethyl 1,2,3,4-tetrahydro-4-(4-methoxyphenyl)-6-methyl-2-oxopyrimidine-5-carboxylat (ETMOC) as a neutral ionophore. The electrode works properly. It responds to Cu2+ ion with a sensitivity of 29.5 ± 0.2 mV/decade over the range 1.0 × 10−9 to 5.0 × 10−1M at p...

The layered van der Waals CuInP2S6 (CIPS) features interesting functional behaviors, including reversible ferroelectric polarization, Cu ion migration, negative capacitance effect, etc. Here, the CIPS flakes were exfoliated from CVT-grown high-quality single crystals, which fabricated into metal/CIPS/metal heterostructures by conventional photolithography. It was found that persisted in dominan...

al3+-potentiometric sensor, based on (2z) -methyl 2- ((z) (p-tolylimino)-3-ethyl -4-oxothiazolidin -5- ylidene) acetate (mteoy) as a neutral ionophore, was successfully developed for the detectionof al3+ in aqueous solutions. the electrode responds to al3+ ion with a sensitivity of 19.8 ± 0.1 mv/decade over the range 1.0 x 10-8- 1.0 x 10-1 mol lt' and in a ph range of 3.0-9.0. the electrodeshow...

In aqueous environment, water-soluble polymers are effectively used to separate free metal ions from metal-polymer complexes. The feasibilities of four different analytical techniques, cadmium ion-selective electrode, dialysis sack, chelate disk cartridge, and ultrafiltration, in distinguishing biopolymer-bound and nonbound cadmium in aqueous samples were investigated. And two different biopoly...

Metal nanowire (MNW) transparent electrodes have been widely developed for their promising sheet resistance (R(s))-transmittance (T) performance, excellent mechanical flexibility, and facile synthesis. How to lower the junction resistance without compromising optical transmittance has become the key issue in enhancing their performance. Here we combine electrospinning and electroless deposition...

tin(ii)-ion-selective electrode consisting of dibenzo-18-crown-6 (db18c6) as an ionophore inpvc matrix was developed. the influences of membrane composition, selectivity, response time,reversibility and temperature on the electrode performance were investigated. the electrodeshowed a near nernstian response for sn2+ ions over a concentration range from 1.0× 10-6 – 1.0× 10-2 m with a slope of 27...