the activation of carbon monoxide by oxygen on mg(100) surface has been investigated by x-ray photoelectron spectroscopy (xps). carbon monoxide is only weakly adsorbed (dispersion-type forces) on a magnesium surface. the xps result has shown that the dissociation of carbon monoxide leading to the formation of a metastable surface carbonate species occurs through the participation of an oxygen s...

In previous papers (1, 2) it has been shown that in dilute aqueous solutions aldehydes may be oxidized in the a! position by oxidizing agents such as ceric sulfate, potassium dichromate, and potassium ferricyanide. Normal butyraldehyde and isobutyraldehyde yielded the most conclusive results; the latt,er was converted by ceric sulfate at 80’ into cr-hydroxyisobutyraldehyde and acetone. The evol...

The effects of solution pH and anion adsorption for the formic acid oxidation reaction on the Pt(111) electrode have been examined using electrochemical techniques. Regarding the pH effects, it has been found that oxidation currents for this reaction increases as the pH increases, which indicates that solution formate is involved in the reaction mechanism. Unexpectedly, the adsorption of sulfat...

The present work aimed to evaluate capability of a new molecular structure to stabilize polyethylene against thermal oxidation. Hence, effects of 3,3-bis(4-hydroxy-2-methyl-5-propan-2-ylphenyl)-2-benzofuran-1-one (thymolphthalein) on thermo-oxidative stability of high density polyethylene (HDPE) in both solid and melt states were investigated and compared with those of SONGNOX 1010, a comme...

One of the principal air pollutants is sulfur dioxide (SO2). The removal of SO2 from flue gas has been one of the key challenges in the control of SO2 emission. In this work, experimental scale photocatalytic oxidation of SO2 is a major process leading to H2SO4 as a new method was suggested on the Liquid ph...

In order to establish the role of magnetic effect in key stages autoxidation and initiated oxidation radical-chain reactions, experimental data kinetic analysis influence a field on oxidative transformations adrenaline are presented this work. case autoxidation, process is being controlled by rate consumption gross quinoid oxidation. The obtained results estimative based assumption leading supe...

Chance (1) has proposed that the peroxidase-catalyzed oxidation of diiydroxyfumaric acid proceeds in two steps. The first step is the oxidation of the hydrogen donor by oxygen, the reaction being catalyzed by a manganese-activated peroxidase and accompanied by the production of hydrogen peroxide. The second step is the oxidation of additional hydrogen donor by hydrogen peroxide, this reaction a...

Major pollutants emission from Direct-Injection (D.I) diesel engines are predicted by means of a mathematical model. In order to construct such a model, an integral Multi-Zone Combustion Model (MZCM) is formulated, which basically consists of jet mixing and combustion submodels. In MZCM, variation of injection pressure is considered. Also time period of ignition delay is predicted by considerin...

Ammonia nitrogen wastewater (about 100 mg/L) was treated by two-stage ozone oxidation method. The effects of ozone flow rate and initial pH on ammonia removal were studied, and the mechanism of ammonia nitrogen removal by ozone oxidation was discussed. After the primary stage of ozone oxidation, the ammonia removal efficiency reached 59.32% and pH decreased to 6.63 under conditions of 1 L/min o...

mn(ii) salen complex immobilized on nano silicagel was prepared by incorporating mn(ii) salen complex into a nanosilica matrix and characterized by tga, xrd, atomic absorption spectroscopy and was successfully applied as catalyst for the oxidation of alcohols. oxidation of a series of alcohols in acetonitrile over immobilized mn(ii) salen complex using tetrabutylammonium peroxymonosulfate (tbao...