A high-precision SIMS analysis technique has been established for oxygen, sulfur, and iron isotope ratios and applied to a wide range of geoscience research areas using a Cameca IMS-1280 at the Wisconsin Secondary Ion Mass Spectrometer Laboratory (WiscSIMS). Precision and accuracy of 0.3‰ is achieved routinely for the measurement of 18O/16O ratio using multicollection Faraday Cup (FC) detectors...

Under anoxic conditions, zerovalent iron (Fe(0)) reduces nitrate to ammonium and magnetite (Fe3O4) is produced at near-neutral pH. Nitrate removal was most rapid at low pH (2-4); however, the formation of a black oxide film at pH 5 to 8 temporarily halted or slowed the reaction unless the system was augmented with Fe(2+), Cu(2+), or Al(3+). Bathing the corroding Fe(0) in a Fe(2+) solution great...

In this work, an adsorbent was prepared based on the attachment of organophosphorus acid extractants, namely, D2EHPA, CYANEX 272, and CYANEX 301, to the surface of superparamagnetic magnetite (Fe3O4) nanoparticles. The synthesized nanoparticles were coated with oleic acid, first by a chemisorption mechanism and later by the respective extractant via physical adsorption. The obtained core-shell ...

The biosynthesis of magnetite is the earliest known example of biomineralisation; however, much of the detailed atomistic mechanisms by which the process occurs are unknown. Within the bacterial strain Magnetospirillum magneticum AMB-1, the formation of magnetite nanoparticles is thought to occur under the influence of the Mms6 protein. The C–terminal of this protein is highly acidic, containin...

Magnetite (Fe3O4) is a potential material for spintronic development due to its high Curie temperature (858 K) and half-metallic structure with only one spin polarization at Fermi level. The bulk properties of Fe3O4 make it big challenge grow perfectly stoichiometric thin films low temperature. Here, we report the structural morphological evolution as function gas flow rate. Radio-frequency (RF...

nowadays nanotechnology as a new direction of science allows us to develop therapeutic methods of the endogenous intoxication syndrome and to create a new class of biocompatible sorbents. in ukraine first preparations of medical nanotechnology were produced and patented in 1998. these are ikbb (intracorporeal biocorrector), magnet-controlled sorbent (mcs-b), and micromage-b. the preparations ar...

Information about potential risks of iron nanomaterials is still limited, while a wide variety of applications are expected. We recently reported acute phase responses of male and female Fischer 344 rats after a single intratracheal spray instillation of Fe3O4 nanoparticles (magnetite), clearly showing dose-dependent pulmonary inflammatory changes (Tada et al., J Toxicol Pathol 25, 233-239, 201...

The solvothermal decomposition of iron complexes using the heat-up process enables monodisperse Fe3O4 nanoparticle synthesis. Here, we demonstrate that the high reduction potential capability of alkaline metal reagents in the reductive environment allows for pure magnetite phase formation at 200 ◦C, which is lower than that of typical synthetic method and offers highly crystalline superparamagn...

Targeted delivery of cells and therapeutic agents would benefit a wide range of biomedical applications by concentrating the therapeutic effect at the target site while minimizing deleterious effects to off-target sites. Magnetic cell targeting is an efficient, safe, and straightforward delivery technique. Superparamagnetic iron oxide nanoparticles (SPION) are biodegradable, biocompatible, and ...

Electrodeposition is an important approach that can produce functional compound materials by assembling multiple species at the electrode surface. However, a fundamental understanding of the electrodeposition mechanism has been limited by its complexity and is often gained only through ex situ studies of deposited materials. Here we report on the application of scanning electrochemical microsco...