نتایج جستجو برای: lewis acid

تعداد نتایج: 761908  

2016
Lewis C. Wilkins Benjamin A. R. Günther Melanie Walther James R. Lawson Thomas Wirth Rebecca L. Melen

The activation of π-bonds in diynyl esters has been investigated by using soft and hard Lewis acids. In the case of the soft selenium Lewis acid PhSeCl, sequential activation of the alkyne bonds leads initially to an isocoumarin (1 equiv PhSeCl) and then to a tetracyclic conjugated structure with the isocoumarin subunit fused to a benzoselenopyran (3 equiv PhSeCl). Conversely, the reaction with...

2012
Daniel Winkelhaus Beate Neumann Norbert W. Mitzel

In the field of polyfunctional Lewis acids [1] the preorganisation of the Lewis acidic sites can be achieved employing rigid backbones. Ortho-substituted benzenes [2], peri-substituted naphthalene [3 – 6] and 1,8substituted anthracene [7, 8] offer promising applications as such backbones in the field of host-guest chemistry [9]. Furthermore, these frameworks can induce unusual interactions betw...

Journal: :Journal of Synthetic Organic Chemistry, Japan 1998

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