Lanthanum staining of embryonic chick cell reaggregates reveals an intercellular material composed of fibrils. Fibrillar arrays may be composed of parallel fibrils with a 35 A center-to-center spacing. Fibrils may also be disoriented, long, and tortuous. Newly dissociated cells show little lanthanum staining surface material, but appreciable amounts are present after 6 hr of reaggregation. Exam...

A novel synergistic extraction system was investigated for the possible selective separation of light lanthanoids using an ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, as an extraction solvent and 2-thenoyltrifluoroacetone and 18-crown-6 as extractants. Trivalent lanthanum was efficiently extracted as a cationic ternary complex by the cation-exchange process, wh...

Quasielastic and inelastic neutron scattering have been highlighted as excellent tools for studying the hydration of cement components. Here, the complimentary application of inelastic and time-resolved quasielastic neutron scattering to investigate the reaction kinetics during the crucial first 24 h of hydration will be highlighted. Some recent results include the interaction of tricalcium and...

The understanding and control of early hydration of tricalcium silicate (C₃S) is of great importance to cement science and concrete technology. However, traditional characterization methods are incapable of providing morphological and spectroscopic information about in situ hydration at the nanoscale. Using soft X-ray spectromicroscopy, we report the changes in morphology and molecular structur...

High-pressure experiments and theoretical calculations demonstrate that an iron-rich ferromagnesian silicate phase can be synthesized at the pressure-temperature conditions near the core-mantle boundary. The iron-rich phase is up to 20% denser than any known silicate at the core-mantle boundary. The high mean atomic number of the silicate greatly reduces the seismic velocity and provides an exp...

We report 3 13 μm spectroscopy of 4 comets observed between August 2002 and February 2003: C/2002 O4 (Hönig) on August 1, 2002, C/2002 V1 (NEAT) on Jan. 9 and 10, 2003, C/2002 X5 (Kudo-Fujikawa) on Jan. 9 and 10, 2003, and C/2002 Y1 (Juels-Holvorcem) on Feb. 20, 2003. In addition, we include data obtained much earlier on 69P/Taylor (February 9, 1998) but not previously published. For Comets Tay...

Titanium-doped gallium lanthanum sulfide (Ti:GLS) and gallium lanthanum oxysulfide (Ti:GLSO) glasses have an absorption band at 500–600 nm that cannot be fully resolved because of its proximity to the band edge of the glass. At concentrations 0.5% a shoulder at 980 nm is observed in Ti:GLS but not in Ti:GLSO. The emission spectra of Ti:GLS and Ti:GLSO both peak at 900 nm with lifetimes of 67 an...

A rat model of immediate pulmonary hypersensitivity was used to investigate the permeability changes in the tracheal epithelium produced by aerosol challenge with antigen. The rats were sensitised by the intraperitoneal injection of antigen (dinitrophenyl (DNP19) ovalbumin). Sensitised and control animals were then challenged for 60 minutes with an aerosol of the same antigen, which also contai...

Single-crystal structure refinements on lithium lanthanum zirconate (LLZO; Li7La3Zr2O12) substituted with gallium were successfully carried out in the cubic symmetry space group I [Formula: see text]3d. Gallium was found on two lithium sites as well as on the lanthanum position. Due to the structural distortion of the resulting Li6.43(2)Ga0.52(3)La2.67(4)Zr2O12 (Ga-LLZO) single crystals, a redu...

induction of systemic resistance to cucumber against marginal leaf blight disease caused by pseudomonas marginalis using silicon application (as 1 &2 mm of sodium silicate) was studied under greenhouse conditions. results indicated that application of 2 mm of sodium silicate remarkably increased resistance in cucumber against the pathogen. according to the results, disease severity in plants tr...