the oxidation of complexes of ti(iii), (til6)3+ (l=ur, meur, dmeur, deture, n-bu-ur, and phur), by iodine as i3- in ethanol and acetonitrile solutions, appears to proceed as a second order reaction and is much faster in ethanol solution (where solvolysis occurs) than in acetonitrile. the enthalpy of activation appears to decrease as ligand's size increases which suggest that the kinetic stabili...

high solid content poly (styrene-co-butyl acrylate) latex ( with 20% and 40% solid content) including high amounts of cloisite 30b (7 wt% and 10 wt%) were kinetically investigated. gravimetric method via measuring the rate of polymerization, number of particles and average number of radicals per particle was used. results showed that by increasing the solid content; the average diameter of poly...

Thermal stability and the kinetics of the grain growth of nano-crystalline Mg-6Al-1Zn-1Si alloy prepared via mechanical alloying (MA) were investigated. It started with elemental powders, using a variety of analytical techniques including differential scanning calorimetry (DSC), X-ray diffraction method (XRD), and scanning electron microscopy (SEM) coupled with energy dispersive spectrometry (E...

Processing of gold ores with high sulfide minerals is problematic as they consume cyanide and reduce gold leaching. Optimization of gold leaching and cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, their leaching kinetics, and speciation of cyanide complexes that consume the free cyanide and compete with gold. In this paper, a physico-chemical approach i...

In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...

Abstract: nanocrystalline nickel samples with the grain size of ~25 nm were prepared via direct current electrodeposition andaluminized for different durations by pack cementation method at 500 means of SEM, EDS and XRD techniques. According to results, short time aluminizing resulted in the formation of asingle aluminide layer whereas at long duration two distinct aluminide layers were formed....

The evaluation of texture as a function of recrystallization has been characterized for directly cold rolled Al-6Mg, Al-6Mg-0.4Sc and Al-6Mg-0.4Sc-0.2Zr alloys. Samples were annealed isothermally at 400 °C for 1 to 240 minutes to allow recrystallization. Recrystallization kinetics of the alloys is analyzed from the micro-hardness variation. Isothermally annealed samples of aluminum alloys were ...

Chemically patterned surfaces have been successfully employed to direct the kinetics of self-assembly of block copolymers into dense, periodic morphologies (”chemoepitaxy”). Significant efforts have been directed towards understanding the kinetics of structure formation and, particularly, the formation and annihilation of defects. In the present manuscript we use computer simulations of a soft,...