We report model calculations on DNA single strands which describe the equilibrium dynamics and kinetics of hairpin formation and melting. Modeling is at the level of single bases. Strand rigidity is described in terms of simple polymer models; alternative calculations performed using the freely rotating chain and the discrete Kratky-Porod models are reported. Stem formation is modeled according...

Many kinetics studies on methanolysis assumed the reactions to be irreversible. The aim of the present work was to study the dynamic modeling of reversible methanolysis of Jatropha curcas oil (JCO) to biodiesel. The experimental data were collected under the optimal reaction conditions: molar ratio of methanol to JCO at 6 : 1, reaction temperature of 60°C, 60 min of reaction time, and 1% w/w of...

rice is one of the most widely human consumed agricultural products. for a prevention or diminishing of rice cracking in its milling process, precision control of drying conditions is indispensable. in this research, a thin layer experimental dryer is employed to obtain paddy’s drying kinetics. drying experiments were conducted at five inlet temperatures of drying air of 30, 40, 50, 60 and 70 °...

The new generations of multi-core chipset architectures achieve unprecedented levels of computational power while respecting physical and economical constraints. The cost of this power is bewildering program complexity. Atmospheric modeling is a grand-challenge problem that could make good use of these architectures if they were more accessible to the average programmer. To that end, software t...

platinum extraction from different secondary sources has been experimentally tested by many researchers. in this article, dissolution of platinum in aqua-regia solution from two types of spent catalysts (reforming and nitric acid production) was kinetically studied. a variety of kinetic models for heterogeneous solid-liquid reactions, including homogeneous diffusion model, shrinking core model,...

We evaluated the accuracy and precision of the CENTURY soil organic matter model for predicting soil organic carbon (SOC) sequestration under rainfed corn-based cropping systems in the US. This was achieved by inversely modeling long-term SOC data obtained from 10 experimental sites where corn, soybean, or wheat were grown with a range of tillage, fertilization, and organic matter additions. In...

recently, the use of biological absorbent in removal of hazardous pollutants such as heavy metals has increased because of the decrease in sludge problems, economical issues, high efficiency and compatibility with the environment. this study was done over the biosorption of nickel by biosolids obtained from the municipal wastewater treatment in a batch reactor. the pretreatment of the biosolids...

in the present study, different activated carbons were prepared from carbonized african beech wood sawdust by potassium hydroxide activation. the activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetric analyzer. the phenol adsorption capacity of the prepared carbons was evaluated. the different ...

3.8.2. Temperature Distribution Measurements 4749 3.8.3. Two-Phase Visualization 4750 3.8.4. Experimental Validation 4751 3.9. Modeling the Catalyst Layer at Pore Level 4751 3.10. Summary and Outlook 4752 4. Direct Methanol Fuel Cells 4753 4.1. Technical Challenges 4754 4.1.1. Methanol Oxidation Kinetics 4754 4.1.2. Methanol Crossover 4755 4.1.3. Water Management 4755 4.1.4. Heat Management 475...

kinetics of single cell protein production from natural gas by a microorganism (a methylomonas sp.) was studied experimentally and by modeling at equal amount of air and natural gas. kinetic models of monod, moser, teissier, aiba, andrews, and noack were used for illustrating cell growth. methane and oxygen were considered as limited substrates with concentration in the range 2-10 mg/lit. death...