Here we propose a thermoresponsive polymer PNIPAM modulated fluorescence resonance energy transfer (FRET) system to enhance the temperature sensitivity of upconversion nanophosphors (UCNPs). By utilizing red/near-infrared dual emitting NaLuF4:Mn(2+),Ln(3+) (Ln(3+) = Yb(3+), Er(3+), Tm(3+)) UCNPs as the energy donor and Au nanoparticles as the acceptor, the temperature resolution of the UCNPs is...

A combination of static and dynamic laser light scattering has revealed that at temperatures higher than ,33 ±C a linear poly(N-isopropylacrylamide) chain grafted with poly(ethylene oxide) (PNIPAMg-PEO) in water can undergo a “coil-to-globule” transition to form a stable single chain core-shell nanostructure with the collapsed PNIPAM chain backbone as the hydrophobic core and the grafted PEO br...

Poly(styrene)-b-poly(N-isopropylacrylamide) (PS-b-PNIPAM) amphiphilic diblock copolymers were synthesized via reverse iodine transfer polymerization (RITP) firstly. And then the honeycomb structured porous films were fabricated by drop the amphiphilic diblock copolymer solutions on glass substrates. The porous films were characterized using field emission scanning electron microscopy (FESEM) an...

Designer particles synthesized by surfactant-free emulsion polymerization were adsorbed successfully on the sapphire discs. The particles carried a thin layer of an atom transfer radical polymerization (ATRP) initiator on the surface and were subsequently successfully used to graft PNIPAAM brushes from the surface. The surface coverage of the discs by these particles could be improved by heat t...

We studied the thermal diffusion behavior of poly(N-isopropylacrylamide) (PNiPAM) in ethanol in a temperature range from T = 14.0 degrees C to T = 40.0 degrees C by means of thermal diffusion forced Rayleigh scattering. The obtained Soret coefficient S(T) of PNiPAM was positive for lower temperatures (T < 34 degrees C), while S(T) showed a negative value for higher temperatures (T > 34 degrees ...