The development of catalysts with earth-abundant elements for efficient oxygen evolution reactions is of paramount significance for clean and sustainable energy storage and conversion devices. Our group demonstrated recently that the electrochemical tuning of catalysts via lithium insertion and extraction has emerged as a powerful approach to improve catalytic activity. Here we report a novel i...

Oxidation of bisphenol-A (BPA) was investigated using a sonophoto Fenton-like hybrid process under visible light irradiation in the presence of iron-containing perovskite LaFeO3 catalysts. For this purpose, firstly the perovskite catalyst (LaFeO3) was prepared by the sol-gel method and calcined at different temperatures (500, 700, and 800 ◦C). The prepared catalysts were characterized using XRD...

The sonochemical decomposition of volatile organometallic compounds produces high surface area solids that consist of agglomerates of nanometer clusters. For iron pentacarbonyl and tricarbonylnitrosylcobalt, nanostructured metals and alloys are formed; for molybdenum hexacarbonyl, the metal carbide is produced. These sonochemically produced nanostructured solids are active heterogeneous catalys...

Synthetic metalloporphyrins, in the presence of monooxygen donors, are known to mimetize various reactions of cytochrome P450 enzymes systems in the oxidation of drugs and natural products. The oxidation of piperine and piplartine by iodosylbenzene using iron(III) and manganese(III) porphyrins yielded mono- and dihydroxylated products, respectively. Piplartine showed to be a more reactive subst...

28 Fenton’s reagent, a solution of hydrogen peroxide and ferrous iron catalyst, is used for an 29 in-situ chemical oxidation of organic contaminants. Sulfuric acid is commonly used to 30 create an acidic condition needed for catalytic oxidation. Fenton’s reaction often involves 31 pressure buildup and precipitation of reaction products, which can cause safety hazards 32 and diminish efficiency....

Iron-functionalized disordered mesoporous silica (FeKIL-2) is a promising, environmentally friendly, cost-effective and highly efficient catalyst for the elimination of volatile organic compounds (VOCs) from polluted air via catalytic oxidation. In this study, we investigated the type of catalytically active iron sites for different iron concentrations in FeKIL-2 catalysts using advanced charac...

The selective oxidation of CH3OH to H2CO over the noble metals Cu, Ag and Au represents one of the oldest industrial catalytic technologies dating back to the 1880s [1,2] and also the first non-Pt based catalytic industrial process. Initially, the catalyst employed for methanol oxidation was metallic Cu and subsequent research three decades later comparing the noble different metal catalysts fo...

supported catalysts synthesized via the interaction of mg(oet)2 with ticl4 in the presence or absence of an internal stereoregulating donor (di-n-butyl phthalate), with different solvents (chlorobenzene, n-undecane, n-heptane) at different titanation temperatures have been studied by a set of physicochemical methods. data on the chemical composition, x-ray structure and pore structure of these ...

Biological wastewater treatment plants (BWWTP) are widely used to treat effluents from chemical process industry. However, there exist refractory substances, such as phenolic compounds, which require previous treatments. Advanced oxidation processes (AOP) are thoroughly being studied as pre-treatment to deal with such phenolic compounds before a BWWTP. Metal salts are widely used as homogeneous...

To gain insight into factors that control H(2)O(2) persistence and ·OH yield in H(2)O(2)-based in situ chemical oxidation systems, the decomposition of H(2)O(2) and transformation of phenol were investigated in the presence of iron-containing minerals and aquifer materials. Under conditions expected during remediation of soil and groundwater, the stoichiometric efficiency, defined as the amount...