The fragmentation of free tenfold protonated ubiquitin in intense 70 femtosecond pulses of 90 eV photons from the FLASH facility was investigated. Mass spectrometric investigation of the fragment cations produced after removal of many electrons revealed fragmentation predominantly into immonium ions and related ions, with yields increasing linearly with intensity. Ionization clearly triggers a ...

We analyze the classical phase space of the hydrogen atom in crossed magnetic and circularly polarized microwave fields in the high frequency regime, u sing the Chirikov resonance overlap criterion and the renormalization map. These methods are used to compute thresholds to large scale chaos and to ionization. The effect of the magnetic field is a strong stabilization of a set of invariant tori...

A Classical Trajectory Monte Carlo (CTMC) simulation has been made of processes of charge exchange and ionization between an hydrogen atom and fully stripped ions embedded in very strong static electric fields (O(10 V/m)), which are thought to exist in cosmic and laser–produced plasmas. Calculations show that the presence of the field affects absolute values of the cross sections, enhancing ion...

The anisotropy and polarization of the cosmic microwave background radiation (CMBR) induced by the scalar and tensor metric perturbations are computed in the long-wavelength limit. It is found that the large-scale polarization of CMBR induced by the decaying tensor mode can reach a few percents. This is different from the scalar or inflation-induced tensor mode, whereas the polarization is at l...

It is demonstrated that tetrahydrofuran (THF) should be used with caution as a solvent in polymer sample preparation for matrix-assisted laser desorption/ionization (MALDI) analyses. The presence of peroxides in THF may cause the oxidation of chemically active groups. This effect is illustrated in the case of S-containing polystyrene derivatives. The oxidation of the trithiocarbonate group resu...

We study vibrational excitations, dissociation, and ionization of H(2)(+) in few-cycle laser pulses over a broad wavelength regime. Our results of numerical simulations supported by model calculations show a many orders-of-magnitude enhancement of vibrational excitation and dissociation (over ionization) of the molecular ion at infrared wavelengths. The enhancement occurs without any chirping o...

a time-of-flight mass spectrometer (tof-ms) developed in our laboratory at isfahan university of technology is described here. the tof-ms instrument uses laser as the ionization source which provides an opportunity to investigate the ions formed in laser ablation or desorption. the tof-ms has an ionization chamber containing an accelerator and an ion lens to focus the ions into a one meter line...

We use classical electron ensembles and the aligned-electron approximation to examine the effect of laser pulse duration on the dynamics of strong-field double ionization. We cover the range of intensities 10(14)-10(16) W/cm2 for the laser wavelength 780 nm. The classical scenario suggests that the highest rate of recollision occurs early in the pulse and promotes double-ionization production i...

Data presented in this article are related with the research article entitled "Effect of soybean phosphatidylcholine on lipid profile of bovine oocytes matured in vitro" [1]. This article describes the differences in the relative abundance of the lipid ions detected by matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) in control and Lα-phosphatidylcholine-treated oocytes....

We present energy-resolved angular distributions of photoelectrons generated in above-threshold ionization (ATI) of nonaligned diatomic molecules N2 and O2 in high-intensity short laser pulses, with emphasis on the most energetic part of the spectra. The angular distribution for photoelectrons with energy of 10U(p) (U(p): ponderomotive energy), i.e., the plateau cutoff in ATI spectra, is found ...