A new PVC membrane mercury(II) ion electrode based on N,N-dimethylformamide-salicylacylhydrazone (DMFAS) as an ionophore is described, which shows excellent potentiometric response characteristics and displays a linear log[Hg(2+)] versus EMF response over a wide concentration range between 6.2 x 10(-7) and 8.0 x 10(-2) M with a Nerstian slope of 29.6 mV per decade and a detection limit of 5.0 x...

A new PVC membrane electrode for the triiodide ion based on a charge-transfer complex of iodine with 7,16-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane as a membrane carrier was prepared. The electrode exhibits a Nernstian response for triiodide ions over a wide concentration range (1.0 x 10(-1)-1.0 x 10(-5) M) with a slope of 59.3 +/- 0.9 mV decade(-1) and a detection limit of 6.3 x 10...

2014 The density distribution of negative hydrogen ions along the axis of a hybrid multicusp Hion source was measured, at different pressures, by using the photodetachement technique. It was found that in the region close to the plasma electrode (first electrode of the extractor) the negative ion density is strongly influenced by the stray magnetic field of the extractor magnets. This stray mag...

A simple process for forming sub-micron gaps between horizontal and vertical electrodes in a three-dimensional micro-electrode system without the need for high-resolution lithography is described. The process is based on the enhancement of ion milling rates in metals at oblique ion incidence, which allows the preferential erosion of metal at a mesa edge. Self-aligned electrode structures are fo...

The work described here comprises the determination of Fe(III) by ion selective potentiometry using a coated-wire ion-selective electrode (CWISE) based on iron–cyclam complex. Linear Nernstian response for this electrode was obtained over the total Fe(III) concentration range of 1× 10−2 to 1× 10−6 M in 0.05 M HNO3, H2SO4, HClO4, HCl, KNO3 and KCl media, with a slope of 60± 5 mV per decade chang...

The ball-like spinel ZnCo2O4 (ZCO) electrode is proposed for capacitive desalination in article number 2100125 by Wei Si and Haibo Li. It exhibits prominent sodium-ion adsorption capacity, such as ultra-high specific capacity remarkable cyclic stability. Most significantly, the mechanism well preferential removal behavior of Na+, K+, Mg2+ ZCO explored.

Clomipramine hydrochloride, active component of an antidepressant drug, was determined in the pharmaceutical formulation by two kinds of potentiometric sensor; a PVC membrane sensor and a carbon paste electrode modified by MWCNTs and ionic liquid. Both sensors were corporated with clomipramine-tetraphenylborate ion-pair complex and they respond based on ion exchange mechanism. The best PVC memb...

The current mainstream energy storage systems are in urgent need of performance improvements to meet novel application requirements. In pursuit a higher density Li-ion and Na-ion batteries, the conventional electrode materials have reached upper limit their theoretical specific capacities. Hence, facile methods reducing irreversible lithium-ion/sodium-ion loss developed further boost battery de...

The electroactive organic materials are promising alternatives to inorganic electrode materials for the new generation of green Li-ion batteries due to their sustainability, environmental benignity, and low cost. Croconic acid disodium salt (CADS) was used as Li-ion battery electrode, and CADS organic wires with different diameters were fabricated through a facile synthetic route using antisolv...

Poly-o-anisidine Sn(IV) arsenophosphate is a newly synthesized nanocomposite material and has been characterized on the basis of its chemical composition, ion exchange capacity, TGA-DTA, FTIR, X-RAY, SEM, and TEM studies. On the basis of distribution studies, the exchanger was found to be highly selective for lead that is an environmental pollutant. For the detection of lead in water a heteroge...